考查了全钒液流电池用离子交换膜PE-01膜和Nafion膜的物理和电化学性能.研究表明:全氟化Nafion膜的离子交换容量和化学稳定性优于PE-01膜, Nafion膜的导电性好,适合大电流充放电,但正、负极钒溶液更易于相互渗透,水的转移较快,电池的库仑效率较低.PE-01均相膜的离子水迁移量与VO.2+扩散性比Nafion膜低.
参考文献
| [1] | 李晓刚,刘素琴,黄可龙,桑商斌,陈立泉.全钒氧化还原液流电池集流体的性能[J].电池,2005(02):93-94. |
| [2] | Mohammadi T;Skyllas Kazacos M .Evaluation of the Chemical Stability of Some Membranes in Vanadium Solution[J].Journal of Applied Electrochemistry,1997,27:153-158. |
| [3] | Mohammadi T;Skyllas Kazacos M .Use of Poly Electrolytes for Incorporation of Ion Exchange Groups in Composite Membranes for Vanadium Redox Flow Battery Applications[J].Journal of Power Sources,1995,56:91-96. |
| [4] | Gab-Jin Hwang;H. Ohya .Preparation of cation exchange membrane as a separator for the all-vanadium redox flow battery[J].Journal of Membrane Science,1996(1):55-67. |
| [5] | T. Mohammadi;M. Skyllas-Kazacos .Preparation of sulfonated composite membrane for vanadium redox flow battery applications[J].Journal of Membrane Science,1995(1/2):35-45. |
| [6] | Theresa Sukkar;Maria Skyllas-Kazacos .Modification of membranes using polyelectrolytes to improve water transfer properties in the vanadium redox battery[J].Journal of Membrane Science,2003(1/2):249-264. |
| [7] | B. Tian;C.W. Yan;F.H. Wang .Proton conducting composite membrane from Daramic/Nafion for vanadium redox flow battery[J].Journal of Membrane Science,2004(1/2):51-54. |
| [8] | T. Mohammadi;M. Skyllas Kazacos .Modification of anion-exchange membranes for vanadium redox flow battery applications[J].Journal of Power Sources,1996(2):179-186. |
| [9] | Mohammadi T.;Skyllaskazacos M. .CHARACTERISATION OF NOVEL COMPOSITE MEMBRANE FOR REDOX FLOW BATTERY APPLICATIONS[J].Journal of Membrane Science,1995(1/2):77-87. |
| [10] | Mohammadi T.;Kazacos MS.;Chieng SC. .WATER TRANSPORT STUDY ACROSS COMMERCIAL ION EXCHANGE MEMBRANES IN THE VANADIUM REDOX FLOW BATTERY[J].Journal of Membrane Science,1997(2):151-159. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%