锌电积长期采用Pb-Ag合金为阳极.该阳极存在析氧过电位高、易腐蚀且污染阴极锌等问题,因此人们研究了各类新型阳极与电积新工艺.综述了铅基多元合金阳极、复合电催化铅基阳极和钛基电催化阳极及Zn-NaClO4联合电解和H2扩散阳极电积的研究与应用现状,展望了锌电积新型阳极与电积新工艺的发展方向.
参考文献
[1] | Li Ping;Cai Qizhou;Wei Bokang .Failure analysis of the impeller of slurry pump used in zinc hydrometallurgy process[J].ENGINEERING FAILURE ANALYSIS,2006,13:876. |
[2] | Gurmen S;Emre M .A laboratory-scale investigation of alkaline zinc electrowinning[J].Minerals Engineering,2003,16:559. |
[3] | 梅光贵;王润德;周敬元.湿法炼锌学[M].长沙:中南大学出版社,2001 |
[4] | 王彦军,谢刚,杨大锦,李永佳,肖婷蔓.降低电积锌直流电耗的现状分析[J].湿法冶金,2005(04):208-211. |
[5] | 梁鹏 .我国锌冶炼现状及技术发展方向分析[分析报告][N].新华社郑州电,2006. |
[6] | 周国宝.让《铅锌行业准入条件》发力[J].中国有色金属,2007(05):4. |
[7] | 吕少祥,戴曦.降低锌电积直流电耗生产实践[J].有色金属(冶炼部分),2001(06):13-15,26. |
[8] | Cachet C;Rerolle C;Wiart R .Kinetics of Pb and Pb-Ag anodes for zinc electrowinning[J].Electrochimica Acta,1996,41(01):83. |
[9] | Ivanov I.;Stefanov Y. .Insoluble anodes used in hydrometallurgy Part I. Corrosion resistance of lead and lead alloy anodes[J].Hydrometallurgy,2000(2):109-124. |
[10] | Ivanov I.;Stefanov Y. .Insoluble anodes used in hydrometallurgy Part II. Anodic behaviour of lead and lead-alloy anodes[J].Hydrometallurgy,2000(2):125-139. |
[11] | 张玉萍.锌电积用阳极的研究与发展[J].湿法冶金,2001(04):169-171. |
[12] | 李松瑞.铅及铅合金[M].长沙:中南工业大学出版社,1996:329. |
[13] | 闵华阳;李冰.锌电解阳极材料的发展[A].,2000:87. |
[14] | 徐瑞东,盘茂森,郭忠诚.锌电积用惰性阳极材料的研究现状[J].电镀与环保,2005(01):4-7. |
[15] | 刘良绅.Pb-Ag-Ca三元合金机械性能的研究[J].矿冶工程,1995(04):61. |
[16] | Le Pape-rerolle C;Petit M A;Wiart R .Catalysis of oxygen evolution on IrOx/Pb anodes in acidic sulfate electrolytes for zinc electrowinning[J].Journal of Applied Electrochemistry,1999,29:1347. |
[17] | Pu Yu;Thomas J. O'Keefe .Evaluation of lead anode reactions in acid sulfate electrolytes I. lead alloys with cobalt additives[J].Journal of the Electrochemical Society,1999(4):1361-1369. |
[18] | 苏向东,罗宏,李鹏,汪大成.电积铜用惰性Pb基合金阳极的工业试验[J].有色金属(冶炼部分),2002(04):43-45. |
[19] | Pu Yu;Thomas J. O'Keefe .Evaluation of Lead Anode Reactions in Acid Sulfate Electrolytes[J].Journal of the Electrochemical Society,2002(5):A558-A569. |
[20] | Rashkov St;Dobrev Ts;Sefanov Y et al.Lead-cobalt anodes for electrowinning of zinc fromsulphate electrolytes[J].Hydrometallurgy,1999,52:223. |
[21] | Stefanov Y;Dobrev Ts .Developing and studying the properties of Pb-TiO2 alloy coated lead composite anodes for zinc electrowinning[J].Transactions of the Institute of Metal Finishing,2005,83(06):291. |
[22] | Petrova M;Stefanov Y;Noncheva Z .Electrochemical behaviour of lead alloys asanodes in zinc electrowinning[J].British Corrosion Journal,1999,34:198. |
[23] | 潘君益,郭忠诚.锌电积用惰性阳极材料的研究现状[J].云南冶金,2004(06):31-35. |
[24] | 杜文明.低银铅钙多元合金阳极板的制造[J].有色金属(冶炼部分),2000(06):46-47. |
[25] | Kwang-Wook Kim;Eil-Hee Lee;Jung-Sik Kim;Ki-Ha Shin;Boong-Ik Jung .A study on performance improvement of Ir oxide-coated titanium electrode for organic destruction[J].Electrochimica Acta,2002(15):2525-2531. |
[26] | 张招贤,唐仁衡,张建华.IrO2·Ta2O5涂层钛阳极的研究和应用[J].广东有色金属学报,2002(02):102-106. |
[27] | 张招贤,张建华.IrO2·Ta2O5涂层钛电极电化学性能的研究[J].广东有色金属学报,2004(02):97-100. |
[28] | 胡吉明,张鉴清,曹楚南.Ti基IrO2+Ta2O5阳极的电化学特性[J].材料研究学报,2002(04):365-370. |
[29] | Hu Jiming;Zhang Jianqing;Cao Chunan .Oxygen evolution reaction on IrO2-based DSAJ type electrodes:kinetics analysis of Tafel lines andEIS[J].International Journal of Hydrogen Energy,2004,29:791. |
[30] | Nijjer S;Thonstad J;Haarberg G M .Cyclic and linear voltammetry on Ti/IrO2-Ta2O5-MnOx electrodes in sulfuric acid containing Mn2+ ions[J].Electrochimica Acta,2001,46:3503. |
[31] | 张招贤.钛电极工学[M].北京:冶金工业出版社,2003 |
[32] | 梁镇海,孙彦平.Ti/SnO2+Sb2O3+MnO2/PbO2阳极的性能研究[J].无机材料学报,2001(01):183-187. |
[33] | 周雍茂.电积用阳极[M].长沙:中南工业大学出版社,1991 |
[34] | 刘业翔.功能电极材料及应用[M].长沙:中南工业大学出版社,1996:238. |
[35] | 苏毅,金作美,代祖元.电解锌的SO2阳极反应动力学[J].中国有色金属学报,2001(03):495-498. |
[36] | M. Wesselmark;C. Lagergren;G. Lindbergh .Methanol Oxidation as Anode Reaction in Zinc Electrowinning[J].Journal of the Electrochemical Society,2005(11):D201-D207. |
[37] | 魏昶,王俊中,姜琪.喷射床电解槽在锌电积中的应用[J].矿冶工程,2001(03):56-58. |
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