利用化学法使化合物NiCl2在室温和氩气气氛中被NaBH4溶液还原,制备出具有纳米尺度的Ni颗粒,并在其表面包覆一层锰氧化物膜,从而制备出具有核/壳结构的铁磁/反铁磁颗粒.在Ni颗粒的合成中加入了分散剂聚丙烯酸(PAA)以避免Ni颗粒团聚;应用热处理手段,对核壳颗粒进行改性.分别通过XRD、TEM、SEM测量手段,对它们进行结构分析,并对这种铁磁/反铁磁的核壳结构样品进行了磁性研究.
参考文献
| [1] | Tarts]P;Morales M P et al.The preparation of magnetic nanoparticles for applications in biomedicine[J].Journal of Applied Physics,2003,36:R182-R197. |
| [2] | Battle X;Labarta A .Finite-sine effects in fine particles:magnetic and transport properties[J].Journal of Physics D:Applied Physics,2002,35:R15-R42. |
| [3] | Frenkel J;Dorfman J .Spontaneous and induced magnetisation in ferromagnetic bodies[J].Nature,1930,126:274-275. |
| [4] | Vazquez M;Luna C;Morales MP;Sanz R;Serna CJ;Mijangos C .Magnetic nanoparticles: synthesis, ordering and properties[J].Physica, B. Condensed Matter,2004(1/4):71-79. |
| [5] | Mallinson JC.The foundations of Magnetic Recording[M].Academic:Berkeley,1987 |
| [6] | Bean C P;Livingston J D .Superparamagnetism[J].Journal of Applied Physics,1959,30:120-129. |
| [7] | Jiang WQ;Yang HC;Yang SY;Horng HE;Hung JC;Chen YC;Hong CY .Preparation and properties of superparamagnetic nanoparticles with narrow size distribution and biocompatible[J].Journal of Magnetism and Magnetic Materials,2004(2/3):210-214. |
| [8] | Gupta AK;Gupta M .Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications[J].Biomaterials,2005(18):3995-4021. |
| [9] | Liao MH.;Chen DH. .Characteristics of magnetic nanoparticles-bound YADH in water/AOT/isooctane microemulsions[J].Journal of molecular catalysis, B. Enzymatic,2002(1/3):81-87. |
| [10] | Wendy Teunissen;Frank M.F.de Groot;John Geus;Odile Stephan;Marcel Tence;Christian Colliex .The Structure of Carbon Encapsulated NiFe Nanoparticles[J].Journal of Catalysis,2001(1):169-174. |
| [11] | Robinson P J;Dunhill P;Lilly M D .The properties of magnetic supports in relation to immobilized Enzyme reactors[J].Bioteclmol and Bioeng,1973,15:603-606. |
| [12] | Bucak S;Jones D A et al.Protein separations using colloidal magnetic nanoparticles[J].Bioteclmol Prog,2003,19:477-484. |
| [13] | Yossi Weizmann;Fernando Patolsky;Oleg Lioubashevski;Itamar Willner .Magneto-Mechanical Detection of Nucleic Acids and Telomerase Activity in Cancer Cells[J].Journal of the American Chemical Society,2004(4):1073-1080. |
| [14] | Weizmann Y;Patolsky F et al.Amplified DNA sensing and immunosensing by the rotation of functional magnetic particles[J].Journal of the American Chemical Society,2003,125:3452-3454. |
| [15] | Mosbach K;Schroder U .Preparation and application of magnetic polymers for targeting of drugs[J].FEBS Letters,1979,102:112-116. |
| [16] | Ramesh S;Kohypin Y et al.Sonochemical deposition and characterization of manophasic amorphous nickel on silica microspheres[J].Chemistry of Materials,1997,9:546-551. |
| [17] | Black C T;Murray C B et al.Spin-dependent tunneling in self-assembled eobalt-nanocrystal superlattiees[J].Science,2000,290:1131-1134. |
| [18] | Koch C C .Synthesis of nanostructured materials by mechanical milling:problems and opportunities[J].Nano-Structured Materials,1997,9:13-22. |
| [19] | Tzitzios V;Basina G;Gjoka M;Alexandrakis V;Georgakilas V;Niarchos D;Boukos N;Petridis D .Chemical synthesis and characterization of hcp Ni nanoparticles[J].Nanotechnology,2006(15):3750-3755. |
| [20] | Kurihara L K;Chow G M;Schoen P E .Nanocrystalline metallic powders and films produced by the polyol method[J].Nanostructured Materials,1995,5:607-613. |
| [21] | Chakroune N.;Viau G.;Ricolleau C.;Fievet-Vincent F.;Fievet F. .Cobalt-based anisotropic particles prepared by the polyol process[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(2):312-318. |
| [22] | Chow G M;Ding J et al.Magnetic and hardness properties of nanostructured Ni-Co films deposited by a nonaqueous electroless method[J].Applied Physics Letters,1999,74:1889. |
| [23] | Yin H;Chow G M .Anomalous electroless polyol deposition of FeNi powders and films[J].Journal of the Electrochemical Society,2002,149:C68-C73. |
| [24] | Ph. TONEGUZZO;G. VIAU;O. ACHER .CoNi and FeCoNi fine particles prepared by the polyol process: Physico-chemical characterization and dynamic magnetic properties[J].Journal of Materials Science,2000(15):3767-3784. |
| [25] | Wang, DP;Sun, DB;Yu, HY;Meng, HM .Morphology controllable synthesis of nickel nanopowders by chemical reduction process[J].Journal of Crystal Growth,2008(6):1195-1201. |
| [26] | Wu S H;Chen D H .Synthesis and Stabilization of Ni Nanopartieles in a Pure Aqueous CTAB Solution[J].Chemistry Letters,2004,33:406. |
| [27] | Olivier Margeat;Catherine Amiens;Bruno Chaudret .Chemical Control of Structural and Magnetic Properties of Cobalt Nanoparticles[J].Chemistry of Materials,2005(1):107-111. |
| [28] | Green M;O'Brien P.The preparation of organically functionalized chromium and nickel nanoparticles[J].Chemical Communications,2001:1912-1913. |
| [29] | Yanglong Hou;Song Gao .Monodisperse nickel nanoparticles prepared from a monosurfactant system and their magnetic properties[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(7):1510-1512. |
| [30] | 李凤生;崔平;杨毅.微纳米粉体后处理技术及应用[M].北京:国防工业出版社,2005:45. |
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