用熔融共混法制备了不同抗氧剂体系改性的玻璃纤维增强尼龙66复合材料,采用热烘箱老化法研究了180℃下老化时间对复合材料高温热氧老化性能影响。结果表明,随着老化时间的延长,未添加抗氧剂的复合材料的拉伸强度和缺口冲击强度保持率显著下降,而添加了1098/168抗氧体系和LS-21抗氧体系的复合材料的相应力学性能保持率明显提高,其中LS-21抗氧体系的效果更佳,对复合材料具有更为优异的初期加工稳定化和长期抗高温热氧老化作用。
Glass fiber reinforced Polyamide 66 composites modified with different compounded antioxidants were prepared,and their high temperature resistant thermal-oxidative aging behaviors were tested and evaluated through heat oven aging method. It has been found that the retention of tensile strength and notched impact strength of the polyamide 66 composite without antioxidants dramatically decreases,but that of the composites modified with 1098/168 and LS-21 antioxidants can be obviously improved,and the LS-21 antioxidant shows a far better effect than 1098/168 and plays a excellent role in the initial process stabilization and long-term high temperature resistant ther-mal-oxidative aging.
参考文献
[1] | 陈金周,王兆麟,屈凌波.玻纤增强尼龙1010的辐射稳定性研究[J].高分子材料科学与工程,1995(02):127-129. |
[2] | 陈金周;张书胜.玻纤增强石油发酵尼龙的热稳定性研究[J].塑料工业,1995(06):23-24. |
[3] | 李荣福,孙涛,胡兴洲.聚酰胺热氧稳定化研究[J].合成材料老化与应用,1998(04):7. |
[4] | 李荣福,胡兴洲.金属杂质对聚酰胺热氧化降解的影响[J].合成材料老化与应用,1999(01):5. |
[5] | Cerruti, P.;Carfagna, C. .Thermal-oxidative degradation of polyamide 6,6 containing metal salts[J].Polymer Degradation and Stability,2010(12):2405-2412. |
[6] | El-Mazry, C.;Ben Hassine, M.;Correc, O.;Colin, X. .Thermal oxidation kinetics of additive free polyamide 6-6[J].Polymer Degradation and Stability,2013(1):22-36. |
[7] | Demco DE;Litvinov VM;Rata G;Popescu C;Phan KH;Schmidt A;Bluemich B .Investigation of thermal aging of polyamide 416 by H-1 solid-state NMR[J].Macromolecular chemistry and physics,2007(19/20):2085-2095. |
[8] | Lanska B. .STABILIZATION OF POLYAMIDES .1. THE EFFICIENCY OF ANTIOXIDANTS IN POLYAMIDE 6[J].Polymer Degradation and Stability,1996(1):89-98. |
[9] | Shu Y;Ye L;Yang T .Study on the long-term thermal-oxidative aging behavior of polyamide 6[J].Journal of Applied Polymer Science,2008(2):945-957. |
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