本文以硅烷、乙炔和氢气为气源,采用热丝CVD法制备了非晶碳化硅薄膜.通过FITR、紫外-可见光分光光度计、四探针仪、台阶仪和霍尔效应测试仪对薄膜的光学和电学性能进行了系统的研究.结果表明,随着乙炔气体流量的增加,薄膜中碳含量和薄膜光学带隙呈现逐渐递增的趋势,其中光学带隙由1.7 eV上升到2.1 eV.同时还发现B掺杂薄膜的空穴浓度随着B2H6与硅烷流量比的增大而显著增大,而霍尔迁移率的变化趋势则与空穴浓度的变化趋势相反,与二者对应的总体效果是薄膜的电阻率首先显著下降,然后缓慢下降至最小值1.94Ω·cm,此后电阻率略有上升.
参考文献
[1] | Bibhu P. Swain;Rajiv O. Dusane .Effect of filament temperature on HWCVD deposited a-SiC: H[J].Materials Letters,2006(24):2915-2919. |
[2] | Shunsuke Ogawa;Masaaki Okabe;Takashi Itoh;Norimitsu Yoshida;Shuichi Nonomura .Amorphous Si_(1-x)C_x:H films prepared by hot-wire CVD using SiH_3CH_3 and SiH_4 mixture gas and its application to window layer for silicon thin film solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2008(5):758-760. |
[3] | Yunaz, I.A.;Nagashima, H.;Hamashita, D.;Miyajima, S.;Konagai, M. .Wide-gap a-Si_(1-x)C_x:H solar cells with high light-induced stability for multijunction structure applications[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2011(1):107-110. |
[4] | Klein S;Dasgupta A;Finger F;Carius R;Bronger T .Electronic properties of low temperature microcrystalline silicon carbide prepared by Hot Wire CVD[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2008(5):630-632. |
[5] | Hitoshi Habuka;Hiroshi Ohmori;Yusuke Ando .Silicon carbide film deposition at low temperatures using monomethylsilane gas[J].Surface & Coatings Technology,2010(9/10):1432-1437. |
[6] | Tabata A;Mori M .Structural changes of hot-wire CVD silicon carbide thin films induced by gas flow rates[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2008(5):626-629. |
[7] | 王丽春,张贵锋,侯晓多,姜辛.热丝法低温制备多晶硅薄膜微结构的研究[J].人工晶体学报,2007(06):1372-1376,1398. |
[8] | Bibhu P S .Influence of Process on HWCVD Deposited a-SiC:H Films[J].Surface and Coatings Technology,2006,201:1132-1i37. |
[9] | Hartel, A.M.;Künle, M.;L?per, P.;Janz, S.;Bett, A.W. .Amorphous Si_xC_(1-x):H single layers before and after thermal annealing: Correlating optical and structural properties[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2010(11):1942-1946. |
[10] | Chao Song;Yunjun Rui;Quanbiao Wang .Structural and electronic properties of Si nanocrystals embedded in amorphous SiC matrix[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2011(9):3963-3966. |
[11] | 贺洁,辛煜,叶超,宁兆元,孙钢.微波电子回旋共振法沉积的非晶碳化硅薄膜结构和性能研究[J].功能材料,2006(12):2010-2013. |
[12] | 江丰,沈鸿烈,鲁林峰,杨超,罗军.Al2O3过渡层厚度对AZO薄膜性能的影响研究[J].电子元件与材料,2010(12):1-4. |
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