以溶胶凝胶法制备了纳米级的Mn-Ce／Ti-CNTs催化剂粉体，考察了有机膨润土，复合硅酸盐水泥，模数为3．6的硅酸钠以及这三种组合的粘结剂对板状催化剂的粘结度、防水性能和脱硝性能的影响。结果表明，单一复合硅酸盐水泥或硅酸钠粘结剂粘结度都不够，单一有机膨润土粘结剂防水性能差；随着粘结剂含量的增多，脱硝性能也相应降低；复合硅酸盐水泥对催化性能的影响小于硅酸钠。优化后得到，6（w）％有机膨润土＋12（w）9，6复合硅酸盐水泥组合的粘结剂，不但能满足一定的粘结度和防水性能。而日拥有最好的脱硝件能。存175℃时，其脱硝忡能可诀80％。250℃的脱硝件能可诀98％以上。
Organo-bentonite, composite portland cement, sodium silicate (3.6 modulus) and their complexes were selected as binders for the formation of pilot scale laminated catalyst of nano-sized MnOx- CeOx/TiO2-CNTs powder prepared by sol-gel method. Effects of different binders on the catalyst adhesion, anti- water solubility and de-NOx activity were studied systematically. Our results indicated that the catalysts formation using composite portland cement and sodium silicate showed sodium silicate decreased the catalyst activity severely. poor adhesions, with a decrease of de-NOx activity, especially The addition of organo-bentonite promoted the catalyst adhesion evidently and kept high de-NOx activity, but exhibited a poor anti-water solubility. By optimizing the binder using their complexes, we found that a binder combination of 6w% organo-bentonite and 12w% composite portland cement showed the highest de-NOx acfvity with good adhesion and waterproof performance, such that a NOx conversion of 80% and 98G were achieved at 175℃ and250℃, respectively.
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