以AlCl3为络合物配体,研究Sm2O3-Eu2O3-Gd2O3的分离特性.结果表明,其传输能力为:Sm≈Gd>Eu,氯化物主要在980~1100 K沉积.不同温区的最大分离系数分别为:βEu/Sm;1200 K=1.70, βEu/Gd; 1300 K=1.88, βSm/Gd; 1300 K=1.24,β'Sm/Eu; 850~880 K=2.76, β'Gd/Eu; 880~900 K=2.83, β'Gd/Sm; 800 K=1.12,高于传统的湿法分离系数.
参考文献
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