欢迎登录材料期刊网

材料期刊网

高级检索

纳米多孔金属镍材料的研制成功,开拓了多孔金属新的应用领域。综述了脱合金法从Ni—Al合金中制备纳米多孔镍材料的必要条件,并十分析了脱元素法和脱相法各自的特点。脱元素法获得的纳米多孔镍的结构是三维无序内部互连通孔结构,而脱相法会产生原有的γ相或γ’相与多孔结构互相交织的网状结构,其中互通孔道大多为几百纳米宽。脱相法是个电化学控制的过程,脱元素法不需要加电压。同时,指出了纳米多孔镍基材料的应用领域及今后的研究方向。

The successful development of nanoporous nickel and nickel alloy materials has opened up new application fields of porous metal. Essential requirement of the nanoporous nickel materials preparaed by dealloying from Ni-AI alloy was reviewed in this paper. The specialties of de-element and de-phase method were also pointed out respectively. Nanop- orous structure of nickel material by de-element method is three-dimensional disordered structure via interconnect, while the de-phase method will produce the original γphase( or γ'-phase) interconnected network structure containing porosity on the nanoscale, which mostly open channels have a few hundred nanometers wide. De-phase is the process of electrochemi- cal control, de-element method does not require the applied voltage. These materials application fields and their develop- ment directions in future were also discussed.

参考文献

[1] Erlebacher,J;Aziz,MJ;Karma,A;Dimitrov,N;Sieradzki,K .Evolution of nanoporosity in dealloying.[J].Nature,2001(6827610):450-453.
[2] Ding Yi;Kim Young Ju;Erlebaehe Jonah .Nanoporous,Gold leaf':"Ancient Teehanology"[J].Advanced Materials,2004,16:1897-1900.
[3] Koczkur Kallum;Yi Qingfeng;Chen Aicheng .Nanoporous Pt-Ru Networks and Their Eetrocatalytical properties[J].Acta Materialia,2007,19:2648-2652.
[4] Ding Yi;Erlebacher Jonah .Nanoporous Metals with Controlled Multimodal Pore Size Distribution[J].Journal of the American Chemical Society,2003,125:7772.
[5] Zhang WY;Li Y N;Fang M.Fabrication of Nanoporous Structure Silver Film by Dealloying of Ag-AI Alloy and Control of Pore Size[A].Montreal:DEStech Publica- tions Inc,2007:325-328.
[6] Hai-Jun Jin;Dominik Kramer;Yulia Ivanisenko;Jorg Weissmuller .Macroscopically Strong Nanoporous Pt Prepared by Dealloying[J].Advanced Engineering Materials,2007(10):849-854.
[7] Devred F;Gieske A H;Adkins N et al.Influence of Phase Com- position and Particle Size of atomised Ni-M Mloy Samples on the Catalytic Performance of Raney-type Nickel Catalysts[J].Applied Catalysis A:General,2009,356:154-161.
[8] Xu Ya;Demura Masahiko;Hirano Toshiyuki .Effect of Alkali Leaching on the Surface Structure of Ni3 A1 Catalyst[J].Applied Su~we Science,2008,254:5413-5420.
[9] Salt lnci;Gtiltekin Selahattin .An Experimental Study on the Ki- neticsof Leaching for the Preparation of a Raney-silver Catalyst[J].Reaction Kinetics and Catalysis Letters,2004,83(02):253-260.
[10] Kukula Pavel;(~erveny Libor .Preparation of Tartaric Acid Modi- fied Raney Nickel Catalyst:Study of Modification Procedure[J].Applied Catalysis A:General,2001,210(1 -2):237-240.
[11] Hao Lei;Zhen Song;Dali Tan;Xinhe Bao;Xuhong Mu;Baoning Zong;Enze Min .preparation of novel Raney-Ni catalysts and characterization by XRD, SEM and XPS[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2001(1):69-76.
[12] 叶金文,刘颖,李芳,连利仙,高升吉,涂铭旌.纳米多孔镍基催化材料的结构与催化性能[J].精细化工,2005(03):192-194.
[13] Hayes J R;Hodge A M;Biener J et al.Monolithic Nanoporous Copper by Dealloying Mn-Cu[J].Journal of Materials Research,2006,21:2611-2616.
[14] Masataka Hakamadaa .orous Ni and Ni-Cu by Alloys[J].Journal,2009,485:583-587.
[15] Li Sun;Chia-Ling Chien;Peter C.Searson .Fabrication of Nanoporous Nickel by Electrochemical Dealloying[J].Chemistry of Materials,2004(16):3125-3129.
[16] Zeis R;Mathur A;Fritz G et al.Platinum-Plated Nanoporous Gold:An efficient,low Pt Loading Electrocatalyst for PEM Fuel Cells[J].Journal of Power Sources,2007,165:65.
[17] Xu C;Su J;Xu X et al.Low Temperature CO Oxidation over Unsupported Nanoporous Gold[J].Journal of the American Chemical Society,2007,129:42.
[18] Zielasek V;Jurgens B;Schulz C et al.Gold Catalysts:Nanopo- rous Gold Foams Angew[J].Chem lnt Ed,2006,45:8241.
[19] Zeis R;Lei T;Sieradzki K et al.Catalytic Reduction of Oxy- gen and Hydrogen Peroxide by Nanoporous Gold[J].Journal of Catalysis,2008,253:132.
[20] Lu-Yang Chen;Jin-Shan Yu;Takeshi Fujita;Ming-Wei Chen .Nanoporous Copper with Tunable Nanoporosity for SERS Applications[J].Advanced functional materials,2009(8):1221-1226.
[21] Gan Yangt .[J].Chinese Journal of Materials Research,2001,15(06):708-710.
[22] Yang Yinghui.[J].Modern Material Dynamics,2005(10):1-3.
[23] Y.N. Li;Z.P. Xi;X.T. Kang .Nanostructured intermetallics prepared by dealloying from single crystal nickel-based superalloys[J].Intermetallics,2009(12):1065-1069.
[24] Joachim Rosier;Debashis Mukherji .Design of Nanoporous Superalloy Membranes for Functional Applications[J].Advanced Engineering Materials,2003(12):916-918.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%