对熔盐电脱氧法(FFC法)的概况和工艺原理进行了简要的介绍,综述了国内外利用该方法制备海绵钛以及其他金属及合金粉末的研究进展.分析了熔盐电脱氧法(FFC法)的优点,并指出了目前该方法遇到的主要问题.指出在今后金属与合金制取工艺的发展趋势上,熔盐电脱氧法将会得到广泛应用并实现工业化.
参考文献
[1] | 周进华.铁合金[M].北京:冶金工业出版社,1993:2. |
[2] | 张烽;于忠.铁合金生产的理论和工艺[M].北京:冶金工业出版社,1994:8. |
[3] | Fray D J;Farthing T W;Chen G Z .Removal of oxygen from oxides and solid solutions by electrolysis in a fused salt[P].GB 9901781,1998-06-05. |
[4] | Chen G Z;Fray D J;Farthing T W .Direct electrochemical reduction of titanium dioxide to titanium in molten calcium chloride[J].NATURE,2000,407(21):361. |
[5] | 王志;袁章福;郭占成 .熔盐电解法直接制备钛合金新工艺探讨[J].有色金属,2003,55(04):32. |
[6] | Chen G Z;Elena G;Fray D J .Direct electrolytic preparation of chromium powder[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,2004,35B(04):223. |
[7] | Katsutoshi Ono;Ryosuke O. Suzuki .A New Concept for Producing Ti Sponge: Calciothermic Reduction[J].JOM,2002(2):59-61. |
[8] | Il Parkb;Takashi Abikoc;Okabea T H .Production of titanium powder directly from TiO2 in CaCl2 through an electronically mediated reaction(EMR)[J].Journal of Physics and Chemistry of Solids,2005,66:410. |
[9] | Okabea T H;Takashi O;Yoshitaka M .Titanium powder production by perform reduction process(PRP)[J].Journal of Alloys and Compounds,2004,364:156. |
[10] | 刘美凤,郭占成,卢维昌.TiO2直接电解还原过程的研究[J].中国有色金属学报,2004(10):1752-1758. |
[11] | 刘美凤 .二氧化钛直接电解提取钛的工艺及机理研究[D].中国科学院过程工程研究所,2005. |
[12] | 李颖君;王淑兰;钟和香 等.电化学还原TiO2反应机理及电极电势的研究[J].有色金属,2003,55(04):68. |
[13] | Wang S L;Li Y J .Roaction mechanism of direct electro-reduction of titanium dioxide in molten calcium chloride[J].Journal of Electroanalytical Chemistry,2004,571:237. |
[14] | George Z. Chen;Derek J. Fray .Voltammetric Studies of the Oxygen-Titanium Binary System in Molten Calcium Chloride[J].Journal of the Electrochemical Society,2002(11):E455-E467. |
[15] | Dring K;Dashwood R;Inman D .Voltammetry of titanium dioxide in molten calcium chloride at 900℃[J].Journal of the Electrochemical Society,2005,152(03):E104. |
[16] | Ma M;Wang D H;Wang W G et al.Extraction of titanium from different titania precursors by the FFC cambridge process[J].Journal of Alloys and Compounds,2006,420:37. |
[17] | 郭胜惠,彭金辉,张世敏,张利波,范兴祥.CaCl2体系中电解还原TiO2制取钛的研究[J].稀有金属,2004(06):1091-1094. |
[18] | NIE Xin-miao,DONG Ling-yan,BAI Chen-guang,CHEN Deng-fu,QIU Gui-bao.Preparation of Ti by direct electrochemical reduction of solid TiO2 and its reaction mechanism[J].中国有色金属学会会刊(英文版),2006(z1):723-727. |
[19] | Yan X Y;Fray D J .Production of niobium powder by direct electrochemical reduction of solid Nb2O5 in a eutectic CaCl2-NaCl melt[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,2005,33B(10):685. |
[20] | Yan XY;Fray DJ .Electrochemical studies on reduction of solid Nb2O5 in molten CaCl2-NaCl eutectic[J].Journal of the Electrochemical Society,2005(10):E308-E318. |
[21] | Yan XY;Fray DJ .Electrochemical studies on reduction of solid Nb2O5 in molten CaCl2-NaCl eutectic[J].Journal of the Electrochemical Society,2005(10):E308-E318. |
[22] | 邓丽琴,许茜,李兵,翟玉春,黄振奇.电脱氧法由Nb2O5直接制备金属铌[J].中国有色金属学报,2005(04):541-545. |
[23] | 胡小锋,许茜.CaCl2-NaCl熔盐电脱氧法制备金属Ta[J].金属学报,2006(03):285-289. |
[24] | 邓丽琴,许茜,马涛,李兵,翟玉春.电脱氧法制铌用Nb2O5阴极活性的改进[J].金属学报,2005(05):551-555. |
[25] | Xu Q;Deng L Q;Wu Y et al.A study of cathode improvement for electro-deoxidation of Nb2O5 in a eutectic CaCl2-NaCl melt at 1073K[J].Journal of Alloys and Compounds,2005,396:288. |
[26] | Elena Gordo;George Z. Chen;Derek J. Fray .Toward optimisation of electrolytic reduction of solid chromium oxide to chromium powder in molten chloride salts[J].Electrochimica Acta,2004(13):2195-2208. |
[27] | Jang K;Hu X H;Ma M et al.Perovskitization--assisted electrochemical reduction of solid TiO2 in molten CaCl2[J].Angewandte Chemie International Edition,2006,45:428. |
[28] | Qiu GH;Ma M;Wang DH;Jin XB;Hu XH;Chen GZ .Metallic cavity electrodes for investigation of powders[J].Journal of the Electrochemical Society,2005(10):E328-E336. |
[29] | 邱国红,汪的华,金先波,胡晓宏,陈政.Cr2O3粉末在CaCl2熔盐中直接电化学还原的金属通腔电极研究[J].电化学,2006(03):304-309. |
[30] | Jin X B;Gao P;Wang D H et al.Electrochemical preparation of silicon and its alloys from solid oxides in molten calcium chloride[J].Angewandte Chemie International Edition,2004,43:733. |
[31] | Wang D H;Qiu G H;Jin X B et al.Electrochemical metallization of solid terbium oxide[J].Angewandte Chemie International Edition,2006,45:2384. |
[32] | Glowacki BA.;Fray DJ.;Yan XY.;Chen G. .Superconducting Nb3Sn intermetallics made by electrochemical reduction of Nb2O5-SnO2 oxides[J].Physica, C. Superconductivity and its applications,2003(1/2):242-246. |
[33] | Glowacki BA.;Yan XY.;Fray D.;Chen G.;Majoros M.;Shi Y. .Niobium based intermetallics as a source of high-current/high magnetic field superconductors[J].Physica, C. Superconductivity and its applications,2002(Pt.3):1315-1320. |
[34] | Qiu GH;Wang DH;Ma M;Jin XB;Chen GZ .Electrolytic synthesis of TbFe2 from Tb4O7 and Fe2O3 powders in molten CaCl2[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2006(1):139-147. |
[35] | Qiu G H;Wang D H;Jin X B et al.A direct electrochemical route from oxide precursors to the terbium-nickel intermetallic compound TbNi5[J].Electroch Acta,2006,51:5785. |
[36] | 朱用,马猛,汪的华,蒋凯,胡晓宏,金先波,陈政.熔盐电还原固态混合氧化物低能耗制备TiNi合金[J].科学通报,2006(16):1966-1970. |
[37] | Dring K;Bhagat R;Jackson M et al.Direct electrochemical production of Ti-10W alloys from mixed oxide preformprecursors[J].J Mloy Comp,2006,419:103. |
[38] | Jamie W M A;Ccpcutt R C;Chen G Z et al.Electrocemical fabrication of nickel manganese gallium alloy powder[J].Advances in Engineering Materials,2003,5(09):650. |
[39] | Andrew J. Fenn;Graham Cooley;Derek Fray .Exploiting the FFC Cambridge Process[J].Advanced Materials & Processes,2004(2):51-53. |
[40] | Fray D J;Chen G Z .Reduction of titanium and other metal oxides using elctrodeoxidation[J].Materials Science and Technology,2004,20(03):295. |
[41] | 徐春森,卢惠民.低成本海绵钛生产新方法[J].钛工业进展,2004(05):44-48. |
[42] | 刘松利,白晨光,杨绍利,陶长元.熔盐电解法制备钛的进展和发展趋势[J].轻金属,2006(12):46-49. |
[43] | 杜继红,奚正平,李争显,刘高建,周慧.电解法制备海绵钛的进展[J].稀有金属快报,2005(01):1-3. |
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