一维链状配合物{[Fe(SO_4)(DPPZ)_2]·H_2O}_n的水热合成及其晶体结构

人工晶体学报, 2010, 39(1): 277-280.

一维链状配合物{[Fe(SO_4)(DPPZ)_2]·H_2O}_n的水热合成及其晶体结构

刘春波 ^1, , 查小林 ^2, , 李秀颖 ^3, , 车广波 ^4, , 李春香 ^5, , 高林 ^6, , 李爱华 ^7,

1.江苏大学化学与化工学院,镇江,212013;吉林师范大学化学学院,四平,136000

2.吉林师范大学化学学院,四平,136000

3.吉林师范大学化学学院,四平,136000

4.江苏大学化学与化工学院,镇江,212013;吉林师范大学化学学院,四平,136000

5.江苏大学化学与化工学院,镇江,212013

6.吉林师范大学化学学院,四平,136000

7.吉林师范大学化学学院,四平,136000

基金项目: 江苏省博士后基金项目(0801010B) 江苏大学自然基金(09JDG001)

关键词：二吡啶[3,2-a: 2',3'-c]并吩嗪 , 水热合成 , 晶体结构

Hydrothermal Synthesis and Crystal Structure of One-dimensional Chain-like Coordination Polymer {[Fe(SO_4)(DPPZ)_2]·H_2O}_n

LIU Chun-bo ^1, , ZHA Xiao-lin ^2, , LI Xiu-ying ^3, , CHE Guang-bo ^4, , LI Chun-xiang ^5, , GAO Lin ^6, , LI Ai-hua ^7,

1.江苏大学化学与化工学院,镇江,212013;吉林师范大学化学学院,四平,136000

2.吉林师范大学化学学院,四平,136000

3.吉林师范大学化学学院,四平,136000

4.江苏大学化学与化工学院,镇江,212013;吉林师范大学化学学院,四平,136000

5.江苏大学化学与化工学院,镇江,212013

6.吉林师范大学化学学院,四平,136000

7.吉林师范大学化学学院,四平,136000

Keywords： dipyrido[3,2-a: 2',3'-c]-phenazine , hydrothermal synthesis , crystal structure

以FeSO_4和二吡啶[3,2-a: 2',3'-c]并吩嗪(DPPZ)为原料,采用水热法合成了一维链状配位聚合物{[Fe(SO_4)(DPPZ)_2]·H_2O}_n,利用元素分析、红外光谱、X射线单晶衍射和热重分析对其结构进行了表征.该配合物属于单斜晶系,P2_1/m空间群,a=1.3569(3) nm,b=0.6519(13) nm, c=1.7250(3) nm, α=90°,β=111.29(3)°,γ=90°,V=1.4217(5) nm~3,Z=2,d_c=1.713 g/cm~3,μ=0.671 mm~(-1),F(000)=750, R_1=0.0491, wR_2=0.1250.

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