Model of Calculating Activity of Nitrogen and Vanadium in Fe-C-V-N Molten Metal

钢铁研究学报(英文版), 2008, 15(5): 19-23.

^1, , ^2, , ^3, , ^4, , ^5, , ^6,

1.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,Beijing,China;School of Metallurgy and Resource,Anhui University of Technology,Ma'anshan 243002,Anhui,China

2.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,Beijing,China

3.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,Beijing,China

4.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,Beijing,China

5.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,Beijing,China

6.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,Beijing,China

基金项目: 国家自然科学基金(50674001)

Model of Calculating Activity of Nitrogen and Vanadium in Fe-C-V-N Molten Metal

PENG Jun ^1, , WANG Shi-jun ^2, , DONG Yuan-chi ^3, , LIU Li-xia ^4, , ZHOU Yun ^5, , CHEN Er-bao ^6,

2.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,Beijing,China

3.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,Beijing,China

4.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,Beijing,China

5.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,Beijing,China

6.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,Beijing,China

Keywords： metal melt

The solubility of nitrogen in the Fe-C-V-N system was measured at 1 708 K and the model of calculating activity (action concentration) of nitroge.n (N) and vanadium (V) was derived according to the phase diagram and the coexistence theory of the metal melt structure.The solubility expression of nitrogen in the Fe-C-V-N system at 1 708 K was wN=0.058 194-0.010 367WC+0.005 543 4wV.Comparing the computing results with the experimental results,a satisfactory conclusion could be obtained.The analysis of the Fe-C-V-N system using this model showed that VN was present in a high temperature metal melt,which would reduce the action concentration of nitrogen obviously.It was consequently disadvantageous to the removal of nitrogen from hot metal.

参考文献

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Model of Calculating Activity of Nitrogen and Vanadium in Fe-C-V-N Molten Metal

参考文献