氧还原合成过氧化氢电极的研究进展

材料导报, 2009, 23(1): 32-35.

氧还原合成过氧化氢电极的研究进展

徐夫元 ^1, , 祝社民 ^2, , 陈英文 ^3, , 宋天顺 ^4, , 沈树宝 ^5,

1.南京工业大学国家生化工程技术研究中心,南京,210009

2.南京工业大学材料科学与工程学院,南京,210009

3.南京工业大学国家生化工程技术研究中心,南京,210009

4.南京工业大学国家生化工程技术研究中心,南京,210009

5.南京工业大学国家生化工程技术研究中心,南京,210009

基金项目: 江苏省省级污染防治专项资金资助项目(2006-1-W-19) 国家高技术研究发展计划(863计划)(20060102Z2009) 江苏省自然科学基金(BK2006181;BK2007188)

关键词：氧还原 , 过氧化氢 , 电极 , 催化剂 , 改性

Research Progress in Synthesis of Peroxide Electrodes with Oxygen-reduction

过氧化氢是一种重要的无机化工产品,在诸多领域得到日益广泛的应用.通过电化学还原氧气在线合成一定浓度过氧化氢的研究受到越来越多研究者的关注.综述了国内外氧还原合成过氧化氢电极的研究进展,包括电极形式、催化剂材料及电极改性方面,并提出今后研发的重点,展望了其发展前景.其中,新型低廉、电化学性能较优催化材料的开发以及修饰电极的制备将是下阶段研究的热点.

参考文献

[1]	Malik P K;Saha S K .[J].Separation and Purification Technology,2003,31(03):241.
[2]	傅坚亮,张兴旺,雷乐成.Fe修饰多壁碳纳米管电极高效产H2O2[J].物理化学学报,2007(08):1157-1162.
[3]	ZiC R R;Strbac S;Anastasijevi N .[J].Materials Chemistry and Physics,1989,22:349.
[4]	Leon C P;Pletcher D .[J].Journal of Applied Electrochemistry,1995,24(04):307.
[5]	Saha M S;Denggerile A;Nishiki Y et al.[J].Electrochemistry Communications,2003,5:445.
[6]	Yamada N;Yaguchi T;Otsuka H .[J].Journal of the Electrochemical Society,1999,146:2587.
[7]	杨凤林 .原位高效电催化生成过氧化氢的电化学反应器[P].中国,200420031310.1,2005-05-11.
[8]	查全性.电极过程动力学导论[M].北京:科学出版社,2002:257.
[9]	Appela M;Applebyb A .[J].Electrochimica Acta,1978,23:1243.
[10]	Yamanaka I;Hashimoto T;Otsuka K .[J].Chemistry Letters,2002,31:852.
[11]	Yamanaka I;Hashimoto T;Takenaka S et al.[J].Angewandte Chemie International Edition,2003,42:3653.
[12]	Baez VB.;Pletcher D. .PREPARATION AND CHARACTERIZATION OF CARBON TITANIUM DIOXIDE SURFACES - THE REDUCTION OF OXYGEN[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,1995(1/2):59-64.
[13]	Sudoh M;Kitaguchi H;Koide K .[J].Journal of Chemical Engineering of Japan,1985,18:409.
[14]	郁青红,周明华,雷乐成.新型气体扩散电极体系高效产H2O2的研究[J].物理化学学报,2006(07):883-887.
[15]	Morcos I;Yeager E .[J].Electrochimica Acta,1970,15:953.
[16]	Paliteiro C;Hamnett A;Goodenough J B .[J].Journal of Electroanalytical Chemistry,1987,233(1-2):147.
[17]	Hossain M S;Tryk D;Yeager E .[J].Electrochimica Acta,1989,34(12):1733.
[18]	Alverez-Gallegos A;Pletcher D .[J].Electrochimica Acta,1998,44(05):853.
[19]	Alverez-Gallegos Alberto;Pletcher Derek .Removal of low level organics via hydrogen peroxide formed in a reticulated vitreous carbon cathode cell. Part 2: The removal of phenols and related compounds from aqueous effluents[J].Electrochimica Acta,1999(14):2483-2492.
[20]	Britto PJ.;Rubio A.;Alonso JA.;Ajayan PM.;Santhanam KSV. .Improved charge transfer at carbon nanotube electrodes[J].Advanced Materials,1999(2):154-157.
[21]	Che G L;Lakshmi R B;Fisher E R et al.[J].Nature,1998,393:346.
[22]	褚有群,马淳安,朱英红.纳米碳管电极上氧的电催化还原[J].物理化学学报,2004(03):331-335.
[23]	Maruyama J;Inaba M;Ogumi Z .[J].Journal of Electroanalytical Chemistry,1998,458(1-2):175.
[24]	Maruyama J;Inaba M;Ogumi M .[J].Electrochimica Acta,1999,45(03):415.
[25]	Mohamed S. El-Deab;Takeo Ohsaka .Hydrodynamic voltammetric studies of the oxygen reduction at gold nanoparticles-electrodeposited gold electrodes[J].Electrochimica Acta,2002(26):4255-4261.
[26]	Otsuka K;Yamanaka I.[J].Electrochimica Acta,1990(35):319.
[27]	El-Deab M S;Ohsaka T .[J].Electrochemistry Communications,2002,4(04):288.
[28]	El-Deab M S;Ohsaka T .[J].Electrochimica Acta,2004,49:2189.
[29]	董国孝;李纪生;庄瑞舫 .[J].分子催化,1996,10(01):19.
[30]	Huissoud A;Tissot P .[J].Journal of Applied Electrochemistry,1998,28:653.
[31]	Huissoud A;Tissot P .[J].Journal of Applied Electrochemistry,1999,29:11.
[32]	Vaik K;Maeorg U;Maschion F C et al.[J].Electrochimica Acta,2005,50:5126.
[33]	Manisankar P;Gomathi A .Electrocatalysis of oxygen reduction at polypyrrole modified glassy carbon electrode in anthraquinone solutions[J].Journal of molecular catalysis, A. Chemical,2005(1/2):45-52.
[34]	Nguyen-Cong H;Gautier J L;Chartier P .[J].Electrochimica Acta,2003,48:2389.
[35]	Sarapuua A;Vaika K;Schiffrinb D J et al.[J].Journal of Electroanalytical Chemistry,2003,541:23.
[36]	Forti JC;Rocha RS;Lanza MRV;Bertazzoli R .Electrochemical synthesis of hydrogen peroxide on oxygen-fed graphite/PTFE electrodes modified by 2-ethylanthraquinone[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2007(1/2):63-67.
[37]	Baez V B;Pletcher D .[J].Journal of Electroanalytical Chemistry,1994,377(1-2):231.
[38]	Zuo G F;Yuan H Q;Yang J D .[J].Journal of Molecular Catalysis A:Chemical,2007,269:46.
[39]	陆兆锷.聚邻苯二胺膜电极上氧还原为过氧化氢[J].电化学,1995(02):214.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

氧还原合成过氧化氢电极的研究进展

Research Progress in Synthesis of Peroxide Electrodes with Oxygen-reduction

参考文献