综述了国内外有关TiO2空心微球制备方法的研究进展,包括模板法、Ostwald熟化法、LBL自组装法、喷雾反应法等,介绍了这些方法制备空心微球的基本原理,结合实例举证探讨了上述各种方法的优缺点,展望了这一领域未来的研究热点和发展方向.
参考文献
| [1] | Wen CE;Xu W;Hu WY;Hodgson PD .Hydroxyapatite/titania sol-gel coatings on titanium-zirconium alloy for biomedical applications.[J].Acta biomaterialia,2007(3):403-410. |
| [2] | Xinchen Wang;Jimmy C.Yu;Chunman Ho;Yidong Hou;Xianzhi Fu .Photocatalytic Activity of a Hierarchically Macro/ Mesoporous Titania[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(6):2552-2559. |
| [3] | Yaoming Xiao;Jihuai Wu;Gentian Yue;Guixiang Xie;Jianming Lin;Miaoliang Huang .The preparation of titania nanotubes and its application in flexible dye-sensitized solar cells[J].Electrochimica Acta,2010(15):4573-4578. |
| [4] | Patricia M.Tenorio Cavalcante;Michele Dondi;Guia Guarini .Ceramic application of mica titania pearlescent pigments[J].Dyes and Pigments,2007(1):1-8. |
| [5] | Chen R;Wang J;Wang H et al.Photocatalytic degradation of methyl orange in aqueous solution over titania-pillared α-zirconium phosphate[J].Solid State Sciences,2011,13(03):630. |
| [6] | Xin Zhang;Qingquan Liu .Visible-light-induced Degradation Of Formaldehyde Over Titania Photocatalyst Co-doped With Nitrogen And Nickel[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2008(15):4780-4785. |
| [7] | Yu, J.;Hai, Y.;Jaroniec, M. .Photocatalytic hydrogen production over CuO-modified titania[J].Journal of Colloid and Interface Science,2011(1):223-228. |
| [8] | Awati P S;Awate S V;Shah P P et al.Photocatalytic decomposition of methylene blue using nanocrystalline anatase titania prepared by ultrosonic technique[J].Catalysis Communications,2003,4(08):393. |
| [9] | Yu H;Yu J;Cheng B et al.Synthesis,characterization and photocatalytic activity of mesoporous titania nonorod titanate nanotube composites[J].Journal of Hazardous Materials,2007,147(1-2):581. |
| [10] | Kim, S.;Ehrman, S.H. .Photocatalytic activity of a surface-modified anatase and rutile titania nanoparticle mixture[J].Journal of Colloid and Interface Science,2009(1):304-307. |
| [11] | Jian Pan;Gang Liu;Gao Qing (Max) Lu .On the True Photoreactivity Order of {001}, {010}, and {101} Facets of Anatase TiO2 Crystals[J].Angewandte Chemie,2011(9):2133-2137. |
| [12] | Su YR;Yu JG;Lin J .Vapor-thermal preparation of highly crystallized TiO2 powder and its photocatalytic activity[J].International Journal of Quantum Chemistry,2007(7):2080-2087. |
| [13] | Mor GK;Shankar K;Paulose M;Varghese OK;Grimes CA .Enhanced photocleavage of water using titania nanotube arrays[J].Nano letters,2005(1):191-195. |
| [14] | Zhang W;Xi Z;Li G et al.Highly ordered coaxial bimodal nanotube arrays prepared by self-organizing anodization on Ti alloy[J].Small,2009,5(15):1742. |
| [15] | Yu HG;Yu JG;Cheng B .Preparation, characterization and photocatalytic activity of novel TiO2 nanoparticle-coated titanate nanorods[J].Journal of molecular catalysis, A. Chemical,2006(1/2):99-106. |
| [16] | Xiaoxiao Yu;Jiaguo Yu;Bei Cheng .Synthesis of Hierarchical Flower-like AlOOH and TiO2/AlOOH Superstructures and their Enhanced Photocatalytic Properties[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(40):17527-17535. |
| [17] | Li XX;Xiong YJ;Li ZQ;Xie Y .Large-scale fabrication of TiO2 hierarchical hollow spheres[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2006(9):3493-3495. |
| [18] | Jiaguo Yu;Shengwei Liu;Huogen Yu .Microstructures and photoactivity of mesoporous anatase hollow microspheres fabricated by fluoride-mediated self-transformation[J].Journal of Catalysis,2007(1):59-66. |
| [19] | JIAGUO YU;XIAOXIAO YU .Hydrothermal Synthesis and Photocatalytic Activity of Zinc Oxide Hollow Spheres[J].Environmental Science & Technology: ES&T,2008(13):4902-4907. |
| [20] | 李纲,刘昉,阳启华,张昭.Si掺杂对TiO2空心微球微结构和光催化性能的影响[J].催化学报,2011(02):286-292. |
| [21] | Akhmad Syoufian;Yuko Inoue;Mitsunori Yada .Preparation of submicrometer-sized titania hollow spheres by templating sulfonated polystyrene latex particles[J].Materials Letters,2007(7):1572-1575. |
| [22] | Chunyan Song;Wujiang Yu;Bin Zhao .Efficient fabrication and photocatalytic properties of TiO2 hollow spheres[J].Catalysis Communications,2009(5):650-654. |
| [23] | Debao Wang;Caixia Song;Yusheng Lin .Preparation and characterization of TiO_2 hollow spheres[J].Materials Letters,2006(1):77-80. |
| [24] | Li HQ;Ha CS;Kim I .Facile fabrication of hollow silica and titania microspheres using plasma-treated polystyrene spheres as sacrificial templates[J].Langmuir: The ACS Journal of Surfaces and Colloids,2008(19):10552-10556. |
| [25] | Xiaoming Sun;Junfeng Liu;Yadong Li .Use of Carbonaceous Polysaccharide Microspheres as Templates for Fabricating Metal Oxide Hollow Spheres[J].Chemistry: A European journal,2006(7):2039-2047. |
| [26] | Yanhui Ao;Jingjing Xu;Degang Fu .A simple method for the preparation of titania hollow sphere[J].Catalysis Communications,2008(15):2574-2577. |
| [27] | Zheng, RB;Meng, XW;Tang, FQ .A general protocol to coat titania shell on carbon-based composite cores using carbon as coupling agent[J].Journal of Solid State Chemistry,2009(5):1235-1240. |
| [28] | Yu, JG;Wang, GH .Hydrothermal synthesis and photocatalytic activity of mesoporous titania hollow microspheres[J].The journal of physics and chemistry of solids,2008(5/6):1147-1151. |
| [29] | Li G;Liu F;Zhang Z .Enhanced photocatalytic activity of silica-embedded TiO2 hollow microspheres prepared by one-pot approach[J].Journal of Alloys and Compounds,2010,493(1-2):L1. |
| [30] | Hari Bala;Yanhui Yu;Yishun Zhang .Synthesis and photocatalytic oxidation properties of titania hollow spheres[J].Materials Letters,2008(14):2074-2077. |
| [31] | Yu JG;Liu W;Yu HG .A one-pot approach to hierarchically nanoporous titania hollow microspheres with high photocatalytic activity[J].Crystal growth & design,2008(3):930-934. |
| [32] | Wang Y;Zhou A;Yang Z .Preparation of hollow TiO2 microspheres by the reverse microemulsions[J].Materials Letters,2008,62(12-13):1930. |
| [33] | Yang H G;Zeng H C .Preparation of hollow anatase TiO2nanospheres via Ostwald ripening[J].Journal of Physical Chemistry B,2004,108(11):3492. |
| [34] | Quanjun Xiang;Jiaguo Yu;Bei Cheng;H. C. Ong .Microwave-Hydrothermal Preparation and Visible-Light Photoactivity of Plasmonic Photocatalyst Ag-TiO_(2) Nanocomposite Hollow Spheres[J].Chemistry, an Asian journal,2010(6):1466-1474. |
| [35] | Shengwei Liu;Jiaguo Yu;StephenMann .Spontaneous construction of photoactive hollow TiO_2 microspheres and chains[J].Nanotechnology,2009(32):325606:1-325606:7. |
| [36] | Rachel A.Caruso;Andrei Susha;Frank Caruso .Multilayered Titania, Silica, and Laponite Nanoparticle Coatings on Polystyrene Colloidal Templates and Resulting Inorganic Hollow Spheres[J].Chemistry of Materials,2001(2):400-409. |
| [37] | Shinsuke Nagamine;Akiko Sugioka;Hiroyuki Iwamoto .Formation of TiO2 hollow microparticles by spraying water droplets into an organic solution of titanium tetraisopropoxide (TTIP) - Effects of TTIP concentration and TTIP-protecting additives[J].Powder Technology: An International Journal on the Science and Technology of Wet and Dry Particulate Systems,2008(2):168-175. |
| [38] | Shinsuke Nagamine;Akiko Sugioka;Yasuhiro Konishi .Preparation of TiO_2 hollow microparticles by spraying water droplets into an organic solution of titanium tetraisopropoxide[J].Materials Letters,2007(2):444-447. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%