采用静电纺丝和紫外光还原的方法制备了含纳米银颗粒的明胶纳米纤维,研究了明胶质量分数、硝酸银加入量及光照时间对银颗粒平均直径的影响.结果表明:随着明胶质量分数的减小及AgNO3加入量的增多,银颗粒的平均直径增大;紫外光照初期银颗粒的平均直径随时问的延长而增大,3h后基本不变.银颗粒呈类球形分布在纤维的表面,平均直径为9~20nm.
参考文献
[1] | Reneker D H;Chun I .Nanometre diameter fibres of polymer produced by electrospinning[J].NANOTECHNOLOGY,1996,7(03):216. |
[2] | Seeram Ramakrishna;Kazutoshi Fujihara;Wee-Eong Teo;Thomas Yong;Zuwei Ma;Ramakrishna Ramaseshan .Electrospun nanofibers: solving global issues[J].Materials Today,2006(3):40-50. |
[3] | Kim YW;Lee DK;Lee KJ;Min BR;Kim JH .In situ formation of silver nanoparticles within an amphiphilic graft copolymer film[J].Journal of Polymer Science, Part B. Polymer Physics,2007(11):1283-1290. |
[4] | Xianfeng Li;Xiufeng Hao;Hui Na .preparation of nanosilver particles into sulfonated poly(ether ether ketone) (S-PEEK) nanostructures by electrospinning[J].Materials Letters,2007(2):421-426. |
[5] | H. K. Lee;E. H. Jeong;C. K. Baek .One-step preparation of ultrafine poly (acrylonitrile) fibers containing silver nanoparticles[J].Materials Letters,2005(23):2977-2980. |
[6] | Jin WJ;Jeon HJ;Kim JH;Youk JH .A study on the preparation of poly(vinyl alcohol) nanofibers containing silver nanoparticles[J].Synthetic Metals,2007(10/12):454-459. |
[7] | Xu XY;Yang QB;Wang YZ;Yu HJ;Chen XS;Jing XB .Biodegradable electrospun poly(L-lactide) fibers containing antibacterial silver nanoparticles[J].European Polymer Journal,2006(9):2081-2087. |
[8] | Hong KH .Preparation and properties of electrospun poly (vinyl alcohol)/silver fiber web as wound dressings[J].Polymer engineering and science,2007(1):43-49. |
[9] | 崔海萍,闫军,万红敬.照相明胶在卤化银感光乳剂中的作用[J].材料导报,2006(09):68-72. |
[10] | Zhang Y Z;Ouyang H W;Lim C T et al.Electrospinning of gelatin fibers and gelatin/PCL composite fibrous scaffolds[J].Journal of Biomedical Materials Research Part B:Applied Biomaterials,2005,72(01):156. |
[11] | Huang H H;Ni X P;Loy G L et al.Photochemical formation of silver nanoparticles in poly(N-vinylpyrrolidone)[J].Langmuir,1996,12(04):909. |
[12] | Zhongping Zhang;Lide Zhang;Shixing Wang;Wei Chen;Young Lei .A convenient route to polyacrylonitrile/silver nanoparticle composite by simultaneous polymerization-reduction approach[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(19):8315-8318. |
[13] | Son W K;Youk J H;Park W H .Antimicrobial cellulose acetate nanofibers containing silver nanopartieles[J].Carbohydrate Polymers,2006,65(04):430. |
[14] | Antonio M B Silva;Araujo C B;Sergio S S et al.Silver nanoparticle in situ growth within crosslinked poly (ester-costyrene) induced by UV irradiation:aggregation control with exposure time[J].Journal of Physics and Chemistry of Solids,2007,68(5-6):729. |
[15] | 关蕊.Ag+与明胶的相互作用(一)[J].明胶科学与技术,2002(04):199-206. |
[16] | Yakutik IM;Shevchenko GP;Rakhmanov SK .The formation of monodisperse spherical silver particles[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2004(1/3):175-179. |
[17] | Zhang Q;Wu D Z;Qi S L et al.Preparation of ultra-fine polyimide fibers containing silver nanoparticles via in situ technique[J].Materials Letters,2007,61(19-20):4027. |
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