Size control of BaTiO3 in solid-state reaction between BaCO3 and TiO2 was demonstrated by varying the size of TiO2 and milling conditions of BaCO3. The smaller TiO2 particles had higher surface area, resulting in faster initial reaction. The mechanically milled BaCO3 particles accelerated the diffusion process and decreased the calcinations temperature. It can be deduced from the results that the size control is possible and nano-sized BaTiO3 particles with about 60 nm can be synthesized by using the conventional solid-state reaction between BaCO3 and TiO2.
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