以2D C/SiC复合材料为基底,采用聚合物裂解工艺(Polymer plyen)制备了含硼硅玻璃SiC自愈合涂层.利用扫描电镜对含硼硅玻璃SiC涂层的2D C/SiC复合材料氧化前后的微结构形貌进行了分析.研究了含硼硅玻璃SiC涂层的C/SiC复合材料在静态空气中700℃、1000℃和1200℃下的氧化行为,并分析了涂层层数对C/SiC复合材料氧化行为的影响.结果表明:含硼硅玻璃SiC涂层在该温度下形成的玻璃相可以较好地封填表面缺陷(裂纹和孔洞);并且随温度升高及涂层层数增加,试样在氧化过程中质量减少率降低,氧化后的强度保持率提高.
参考文献
| [1] | 张立同,成来飞.连续纤维增韧陶瓷基复合材料可持续发展战略探讨[J].复合材料学报,2007,24(2):1-6.Zhang Litong,Cheng Laifei.Discussion on strategies of sustainable development of continuous fiber reinforced ceramic matrix composites[J].Acta Materiae Compositae Sinica,2007,24(2):1-6. |
| [2] | Lamouroux E,Bertrand S,Pailler R,et al.Oxidationresistant carbon-fiber-reinforced ceramic-matrix composites[J].Composites Science and Technology,1999,59(7):1073-1085. |
| [3] | Naslain R.Design,preparation and properties of nonoxidation CMCs for application in engines and nuclear reactors:An overview[J].Composites Science and Technology,2004,62(2):155-170. |
| [4] | Tong C Q,Cheng L F,Yin X W,et al.Oxidation behavior of 2D C/SiC composite modified by SiB4 particles in inter-bundle pores[J].Composites Science and Technology,2008,68(3/4):602-607. |
| [5] | Xu Y D,Zhang L T,Cheng L F,et al.Microstructure and mechanical properties of three-dimensional carbon/silicon carbide composites fabricated by chemical vapor infiltration[J].Carbon,1998,36(7/8):1051-1056. |
| [6] | 刘永胜.CVD/CVI法制备B-C陶瓷的工艺基础[D].西安:西北工业大学,2008:23-135. |
| [7] | Goujard S,Vandenbulcke L,Tawil H.Oxidation behaviour of two-and three--dimensional C/SiC thermostructural materials protected by chemical-vapour-deposition polylayers coatings[J].Journal of Materials Science,1994,29(23):6212-6220. |
| [8] | Naslain R,Pailler R,Bourrat X,et al.Synthesis of highly tailored ceramic matrix composites by pressure-pulsed CVI[J].Solid State Ionics,2001,141/142:541-548. |
| [9] | Quemard L,Rebillat F,Guette A,et al.Self-healing mechanisms of a SiC fiber reinforced multi-layered ceramic matrix composite in high pressure steam environments[J].Journal of the European Ceramic Society,2007,27(4):2085-2094. |
| [10] | Vandenbulcke L.Outstanding ceramic matrix composites for high temperature applications[J].Advanced Engineering Materials,2005,7(3):137-142. |
| [11] | Goujard S,Vandenbulcke L,Tawil H.Oxidation behavior of 2D and 3D carbon/carbon thermostructural materials protected by CVD polylayer coatings[J].Thin Solid Films,1994,252(2):120-130. |
| [12] | Li H B,Zhang L T,Cheng L F,et al.UV curing behavior of a highly branched polycarbosilane[J].Journal of Materials Science,2009,44(3):970-975. |
| [13] | Li H B,Zhang L T,Cheng L F,et al.Effect of curing and pyrolysis processing on the ceramic yield of a highly branched polycarbosilane[J].Journal of Materials Science,2009,44(3):721-725. |
| [14] | 成来飞.1650℃长寿命碳/碳复合材料防氧化涂层研究[D].西安:西北工业大学,1997:99. |
| [15] | 吴守军,成来飞,张立同,等.CVD SiC涂层对3D C/SiC氧化行为的影响[J].无机材料学报,2005,20(1):251-256.Wu Shoujun,Cheng Laifei,Zhang Litong,et al.Effect of CVD SiC coatings on oxidation behaviors of three dimensional C/SiC composites[J].Journal of Inorganic Materials,2005,20(1):251-256. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%