锆合金第二相研究述评(Ⅰ):Zircaloys合金

中国有色金属学报, 2012, 22(6): 1594-1604.

锆合金第二相研究述评(Ⅰ):Zircaloys合金

柴林江 ^1, , 栾佰峰 ^2, , 周宇 ^3, , 邱日盛 ^4, , 陈建伟 ^5,

1.重庆大学材料科学与工程学院,重庆400044

2.重庆大学材料科学与工程学院,重庆400044

3.重庆大学材料科学与工程学院,重庆400044

4.重庆大学材料科学与工程学院,重庆400044

5.重庆大学材料科学与工程学院,重庆400044

基金项目: 中央高校基本科研业务费专项资金资助项目(CDJZR10130008;CDJXS10132201) 教育部新世纪优秀人才支持计划资助项目(NCET-08-0606)

关键词： Zircaloys合金 , Laves相 , Zr-Fe-Ni粒子 , Zr-Fe-Cr粒子

Review of second phase particles on zirconium alloys (Ⅰ): Zircaloys

回顾了国内外近几十年来关于Zircaloys合金中第二相粒子本征特征(晶体结构、成分、形状、亚结构等)的相关研究工作.Zircaloys合金中的Zr-Fe-Ni粒子只有一种,即C16(BCT,Al2Cu)型Zr2(Fe,Ni) Zintl相.而Zr-Fe-Cr 粒子主要有两种:一种是C14(HCP,MgZn2)型Zr(Fe,Cr)2 Laves相,另一种是C15(FCC,MgCu2)型Zr(Fe,Cr)2 Laves 相,这些Laves相内部均可见层错结构.归纳总结出形成温度决定论、n(Fe)/n(Cr)决定论、价电子/原子比决定论3种理论,用于解释Zr(Fe,Cr)2粒子形成稳定结构的原因.常规加工工艺下,在Zircaloys合金成分范围内,Sn完全固溶于a-Zr基体,不会参与形成析出相,Fe、Cr,Ni一般也不会单独与Zr形成Zr-Fe、Zr-Cr、Zr-Ni粒子.

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