纳米CuInS_2材料是一种直接带隙半导体材料,其禁带宽度为1.50eV,吸收系数高达10~5cm~(-1),在太阳电池领域有着广阔的应用前景.水热及溶剂热法是液相制备纳米粉体的常用方法之一,其用于制备形貌可控的CuInS_2光伏材料具有独特的优势.介绍了黄铜矿型CuInS_2晶体的结构和性质以及水热及溶剂热法的原理和特点;综述了近年来国内外水热及溶剂热法制备不同形貌与结构CuInS_2光伏材料的研究现状,研究了其制备特点及制备机理;最后探讨了目前存在的问题及今后研究的方向.
Nanostructured copper indium sulfide(CuInS_2)material,a critical semiconductor with a direct band gap of 1.5eV alongside its large absorption coefficient(α～l0~5cm~(-1)),has a good prospect of application in photovoltaic solar cells.As one of the widely used liquid-phase technique to synthesize nanopowders,the hydrothermal and solvothermal approach has attracted significant interest on preparing morphology controllable CuInS_2 photovoltaic materials due to its unique advantage in this respect.The crystal structure and properties of the chalcopyrite CuInS_2,the principle and characteristics of the hydrothermal and solvothermal route are introduced；the recent development on the synthesis of morphology and structure tailored CuInS_2 photovoltaic materials by hydrothermal and solvothermal route is described,its characteristic and preparation mechanism are investigated.At last,the difficulties in the present and the prospect in the future for synthesis of CuInS_2 photovoltaic materials by hydrothermal and solvothermal route are discussed.
参考文献
| [1] | Gorai S;Bhattacharya S et al.Morphology controlled solvothermal synthesis of copper indium sulphide powder and its characterization[J].Materials Letters,2005,59:3535. |
| [2] | Kajari Das;Subhendu K. Panda;Soma Gorai;Pratima Mishra;Subhadra Chaudhuri .Effect of Cu/In molar ratio on the microstructural and optical properties of microcrystalline CuInS_2 prepared by solvothermal route[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2008(10):2742-2750. |
| [3] | Hu Hanmei et al.Large-scale growth of porous CuInS_2 microspheres[J].Inorganic Chemistry Communications,2004,7:563. |
| [4] | Gorai S;Chaudhuri S .Polyol-mediated synthesis of copper indium sulphideby solvothermal process[J].Materials Chemistry and Physics,2005,94:434. |
| [5] | Synthesis Of Copper Indium Sulfide Nanoparticles By Solvothermal Method[J].Materials Letters,2009(13/14):1192-1194. |
| [6] | Feng Jiamin;Han Jianjun et al.Synthesis of CuInS_2 quantum dots on TiO_2 porous films by solvothermal method for absorption layer of solar cellts[J].Progress in Organic Coatings,2009,64:268. |
| [7] | Stephanie L Castro et al.Synthesis and characterization of colloidal CuInS_2 nanoparticles from a molecular singlesource precursor[J].Journal of Physical Chemistry B,2004,108:12429. |
| [8] | Li B.;Huang JX.;Qian YT.;Xie Y. .Synthesis by a solvothermal route and characterization of CuInSe2 nanowhiskers and nanoparticles[J].Advanced Materials,1999(17):1456-1459. |
| [9] | Peng Shengjie;Cheng Fangyi;Liang Jing et al.Facile solution-controlled growth of CuInS_2 thin films on FTO and TiO_2/FTO glass substrates for photovoltaic application[J].Journal of Alloys and Compounds,2009,481:786. |
| [10] | Gou Xinglong;Cheng Fangyi;Shi Yunhui et al.Shape-controlled synthesis of ternary chalcogenide ZnIn_2S_4 and CuIn (S,Se)_2 nano-/microstructures via facile solution route[J].Journal of the American Chemical Society,2006,128:7222. |
| [11] | Nairn JJ;Shapiro PJ;Twamley B;Pounds T;von Wandruszka R;Fletcher TR;Williams M;Wang CM;Norton MG .Preparation of ultrafine chalcopyrite nanoparticles via the photochemical decomposition of molecular single-source precursors[J].Nano letters,2006(6):1218-1223. |
| [12] | Peter M Allen;Moungi G Bawendi .Ternary Ⅰ-Ⅲ-Ⅵ quanturn dots luminescent in the red to near-infrared[J].Journal of the American Chemical Society,2008,130:9240. |
| [13] | Zhong Haizheng;Zhou Yi;Ye Mingfu et al.Controlled synthesis and optical properties of colloidal ternary chalcogenide CuInS_2 nanocrystals[J].Chemistry of Materials,2008,20:6434. |
| [14] | Hiroyuki Nakamura;Wataru Kato;Masato Uehara et al.Tunable photoluminescence wavelength of chalcopyrite CuInS_2-based semiconductor nanocrystals synthesized in a colloidal system[J].Chemistry of Materials,2006,18:3330. |
| [15] | Peng Shengjie;Liang Jing;Zhang Li et al.Shape-controlled synthesis and optical characterization of chalcopyrite CuInS_2 microstmctures[J].Journal of Crystal Growth,2007,305:99. |
| [16] | Matthew G. Panthani;Vahid Akhavan;Brian Goodfellow;Johanna P. Schmidtke;Lawrence Dunn;Ananth Dodabalapur;Paul F. Barbara;Brian A. Korgel .Synthesis of CuInS2, CuInSe2, and Cu(InxGa1-x)Se2 (CIGS) Nanocrystal “Inks” for Printable Photovoltaics[J].Journal of the American Chemical Society,2008(49):16770-16777. |
| [17] | Hergert F;Hock R;Schorr S .Pentanary chalcopyrite compounds without tetragonal deformation in the heptanary system Cu(Al,Ga,In)(S,Se,Te)(2)[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2007(1):44-46. |
| [18] | 李建军,邹正光,龙飞.CIS（CIGS）太阳能电池研究进展[J].能源技术,2005(04):164-167. |
| [19] | Terezia Nyari;Paul Barvinschi;Radu Baies et al.Experimental and numerical results in hydrothermal synthesis of CuInS_2 compound semiconductor nanocrystals[J].Journal of Crystal Growth,2005,275:e2383. |
| [20] | Lu Qingyi;Hu Junqing;Tang Kaibin et al.Synthesis of nanocrystalline CuMS_2(M=In or Ga)through a solvothermal process[J].Inorganic Chemistry,2000,39:1606. |
| [21] | Qi Yunxia;Tang Kaibin;Zeng Suyuan et al.Template-free one-step fabrication of porous CuInS_2 hollow microspheres[J].Microporous and Mesoporous Materials,2008,114:395. |
| [22] | Qi Yunxia;Liu Qiangchun;Tang Kaibin et al.Synthesis and characterization of nanostructured wurtzite CuInS_2:A new cation disordered polymorph of CuInS_2[J].Journal of Physical Chemistry C,2009,113:3939. |
| [23] | Zheng, L;Xu, Y;Song, Y;Wu, CZ;Zhang, M;Xie, Y .Nearly Monodisperse CuInS2 Hierarchical Microarchitectures for Photocatalytic H-2 Evolution under Visible Light[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2009(9):4003-4009. |
| [24] | Jiang Y.;Mo X.;Yu WC.;Xie Y.;Qian YT.;Wu Y. .Elemental solvothermal reaction to produce ternary semiconductor CuInE2 (E = S, Se) nanorods[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2000(14):2964-2965. |
| [25] | Xiao Jianping;Xie Yi;Tang Rui et al.Synthesis and characterization of ternary CuInS_2 nanorods via a hydrothermal route[J].Journal of Solid State Chemistry,2001,161:179. |
| [26] | Yu Changlin;Jimmy C Yu;Wen Herui et al.A mild solvothermal route for preparation of cubic-like CuInS_2 crystals[J].Materials Letters,2009,63:1984. |
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