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采用分段电极测量阴极保护下矩形模拟剥离涂层底部Q345钢的电位和电流的分布。研究扰动、溶液氧含量和溶液初始pH值对缝内阴极极化行为的影响。结果表明,扰动作用能够迫使本体溶液中的氧进入缝内,降低缝内Q345钢的阴极极化程度。在低电导率溶液中,扰动作用能够在缝内诱发明显的氧浓差腐蚀电池,加剧缝底部Q345钢的腐蚀。本体溶液氧含量以及溶液初始pH值对缝内Q345钢的最终阴极极化水平影响很小。

Potential and current distributions in a cathodically polarized crevice between a simulated dis- bonded coating and segmented Q345 steels were measured in this paper. The effects of agitation, oxygen concentration and pH value of initial solution on cathodic polarization behavior were studied. The results showed that agitation forced the oxygen in bulk solution to enter the crevice, thus degrading cathodic polariza- tion level of Q345 steels in crevice. In low conductivity solution, agitation caused oxygen concentration cells in crevice, and aggravated corrosion at the rear of crevice. The oxygen concentration and initial solution pH had little influence on the final cathodic polarization level of Q345 steels beneath the simulated disbonded coating.

参考文献

[1] Flavio Deflorian;Stefano Rossi .An EIS study of ion diffusion through organic coatings[J].Electrochimica Acta,2006(8/9):1736-1744.
[2] D. -T. Chin;G. M. Sabde .Current distribution and electrochemical environment in a cathodically protected crevice[J].Corrosion: The Journal of Science and Engineering,1999(3):229-237.
[3] Effect of cathodic protection on corrosion of pipeline steel under disbonded coating[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2009(9):2242.
[4] 闫茂成,王俭秋,柯伟,韩恩厚.埋地管线剥离覆盖层下阴极保护的有效性[J].中国腐蚀与防护学报,2007(05):257-262.
[5] 陈旭,李晓刚,杜翠薇,梁平.阴极极化条件下X70钢的缝隙腐蚀行为[J].金属学报,2008(12):1431-1438.
[6] 闫茂成,翁永基.阴极保护管线破损涂层下高pH环境形成规律[J].中国腐蚀与防护学报,2004(02):95-99.
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