微纳米稀土硫氧化物的合成方法研究进展

中国稀土学报, 2011, 29(6): 643-654.

微纳米稀土硫氧化物的合成方法研究进展

杨利颖 ^1, , 王进贤 ^2, , 董相廷 ^3, , 刘桂霞 ^4, , 于文生 ^5, , 徐佳 ^6,

1.长春理工大学化学与环境工程学院,吉林长春130022

2.长春理工大学化学与环境工程学院,吉林长春130022

3.长春理工大学化学与环境工程学院,吉林长春130022

4.长春理工大学化学与环境工程学院,吉林长春130022

5.长春理工大学化学与环境工程学院,吉林长春130022

6.长春理工大学化学与环境工程学院,吉林长春130022

基金项目: 教育部科学技术研究重点项目(207026) 吉林省科技发展计划重大项目(20070402;20060504) 国家自然科学基金项目(50972020;51072026) 教育部博士点基金项目(20102216110002)

关键词：稀土硫氧化物 , 制备 , 纳米材料

Advancements in Synthesis Methods of Micro-and Nano-Rare Earth Oxysulfides

稀土硫氧化物作为一类重要的发光基质,具有非常高的光吸收和传能效率,是一类重要的光功能材料,被广泛应用在彩色显示、背光源、生物医学等领域,是目前光功能材料领域研究的热点之一.国内外研究者已用先驱物硫化法、氧化物硫化法、水热与溶剂热法、固相反应法、燃烧法、微波法、静电纺丝法等,成功制备了纳米颗粒、纳米管、纳米线、纳米棒、纳米花、多面体纳米晶、纳米纤维和纳米带等稀土硫氧化物纳米材料.总结了上述各种制备方法的研究现状,对其优缺点进行了评述,并结合课题组在稀土硫氧化物纳米材料制备方面的工作,对该类发光材料制备技术的发展方向做了展望.

参考文献

[1]	Tian Y;Cao W H;Luo X X;Fu Y .Preparation and luminescence property of Gd2O2S:Tb X-ray nanophosphors using the complex precipitation method[J].Journal of Alloys and Compounds,2007,433(1-2):313.
[2]	Jüstel T;Nikol H;Ronda C .New developments in the field of luminescent materials for lighting and displays[J].Angewandte Chemie International Edition,1998,37(22):3084.
[3]	Jia, G;You, HP;Liu, K;Zheng, YH;Guo, N;Jia, JJ;Zhang, HJ .Highly Uniform YBO3 Hierarchical Architectures: Facile Synthesis and Tunable Luminescence Properties[J].Chemistry: A European journal,2010(9):2930-2937.
[4]	Ngai T. Lau;Ming Fang;Chak K. Chan .The effect of H2O on the reduction of SO2 and NO by CO on La2O2S[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2008(2):110-116.
[5]	Cavouras D.;Nomicos CD.;Bakas A.;Panayiotakis GS.;Kandarakis I. .Measurement of the (Gd,La)(2)O2S : Tb phosphor efficiency for x-ray imaging applications[J].Radiation measurements,2000(1):5-13.
[6]	Guang-Shun Yi;Gan-Moog Chow .Water-Soluble NaYF4:Yb,Er(Tm)/NaYF4/Polymer Core/Shell/Shell Nanoparticles with Significant Enhancement of Upconversion Fluorescence[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(3):341-343.
[7]	侯远,董相廷,王进贤,刘桂霞.稀土氟化物微纳米材料制备方法的研究进展[J].中国稀土学报,2010(05):515-524.
[8]	Wang, F;Yang, B;Zhang, JC;Dai, YN;Ma, WH .Highly enhanced luminescence of Tb3+-activated gadolinium oxysulfide phosphor by doping with Zn2+ ions[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2010(3):473-477.
[9]	徐时清,杨中民,戴世勋,杨建虎,温磊,胡丽丽,姜中宏.Spectral Properties of Erbium-Doped Oxyfluoride Silicate Glasses for Broadband Optical Amplifiers[J].中国物理快报(英文版),2003(06):905-908.
[10]	Wang M;Abbineni G;Clevenger A;Mao C,Xu S.Upconversion nanoparticlos:synthesis,surface modification and biological applications[M].Nanomodicine:NBM,2011:1.
[11]	张俊文,谭宁会,刘应亮,满石清.沉淀法合成纳米晶上转换发光材料Y_2O_2S：Yb,Er[J].无机化学学报,2010(02):229-232.
[12]	Pires A M;Serra O A;Davolos .Yttrium oxysulfide nanosized spherical particles doped with Yb and Er or Yb and Tm:efficient materials for up-converting phosphor technology field[J].Journal of Alloys and Compounds,2004,374(1-2):181.
[13]	P.F. Ai;W.Y. Li;L.Y. Xiao;Y.D. Li;H.J. Wang;Y.L. Liu .Monodisperse nanospheres of yttrium oxysulfide: Synthesis, characterization, and luminescent properties[J].CERAMICS INTERNATIONAL,2010(7):2169-2174.
[14]	杨志平,刘冲,郭智,冯建伟,杨勇,李兴民.红色Y2O2S：Eu3+磷光材料的沉淀法制备和发光性能研究[J].河北大学学报（自然科学版）,2004(06):585-588,593.
[15]	杨志平,李兴民,杨勇,李旭,李盼来.共沉淀法制备Y2 O2 S：EU3+,Mg2+,Ti4+红色长余辉材料[J].发光学报,2006(02):187-190.
[16]	Michael Nazarov;Jong Hyuk Kang;Duk Young Jeon;Sergey Bukesov;Tatiana Akmaeva .Synthesis and luminescent performances of some europium activated yttrium oxide based systems[J].Optical materials,2005(10):1587-1592.
[17]	Dhanaraj J.;Geethalakshmi M.;Jagannathan R.;Kutty TRN. .Eu3+ doped yttrium oxysulfide nanocrystals - crystallite size and luminescence transition(s)[J].Chemical Physics Letters,2004(1/3):23-28.
[18]	Thirumalai J;Chandramohan R;Sekar M;Rajachandrasekar R .Eu3+ doped yttrium oxysulfide quantum structures-structural, optical and electronic properties[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,2008(3):455-463.
[19]	李丹,吕少哲,王海宇,陈宝玖,鄂书林,张家骅,黄世华.Y2O2S纳米晶中Tb3+发光的浓度猝灭[J].发光学报,2001(03):227-231.
[20]	欧阳芳平,唐波.Y2O2S：Tb纳米晶的能量传递过程的研究[J].稀有金属材料与工程,2003(07):522-525.
[21]	Up-conversion luminescence properties of Y_2O_2S:Yb~(3+),Er~(3+) nanophosphors[J].Optical materials,2009(12):1787.
[22]	J. Llanos;V. Sanchez;C. Mujica;A. Buljan .Synthesis, physical and optical properties, and electronic structure of the rare-earth oxysulfides Ln_2O_2S (Ln = Sm, Eu)[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2002(14):2285-2291.
[23]	Fu, Y.;Cao, W.;Peng, Y.;Luo, X.;Xing, M. .The upconversion luminescence properties of the Yb~(3+)-Ho ~(3+) system in nanocrystalline Y_2O_2S[J].Journal of Materials Science,2010(23):6556-6561.
[24]	Zhang Y;Li Y D .Red photoluminescence properties and crystal structure of sodium rare earth oxyborate[J].Journal of Alloys and Compounds,2004,307(1-2):99.
[25]	Chen Y;Yuan HM;Tian G;Zhang GH;Feng SH .Hydrothermal synthesis and magnetic properties of RMn2O5 (R = La, Pr, Nd, Tb, Bi) and LaMn2O5+delta[J].International Journal of Quantum Chemistry,2007(4):1340-1346.
[26]	张颂 .特殊形貌稀土纳米发光材料的合成及其性能研究[D].长春理工大学,2009.
[27]	Jiang Y.;Wu Y. .Synthesis and Characterization of Nanocrystalline Lanthanide Oxysulfide via a La(OH)_3 Gel Solvothermal Route[J].Journal of the American Ceramic Society,2000(10):2628-2630.
[28]	Song Y H;You H P;Huang Y J;Yang M Zheng Y H Zhang L H Guo N .Highly uniform and monodisperse Gd2O2S:Ln3+(Ln =Eu,Tb)submicrospheres:sclvothermal synthesis and luminescence properties[J].Inorganic Chemistry,2010,49(24):11499.
[29]	Zhao F;Yuan M;Zhang W;Gao S .Monodisperse lanthanide oxysulfide nanoctystals[J].Journal of the American Chemical Society,2006,128(36):11758.
[30]	Hang T;Liu Q;Mao DL;Chang CK .Long lasting behavior of Gd2O2S : Eu3+ phosphor synthesized by hydrothermal routine[J].Materials Chemistry and Physics,2008(1):142-147.
[31]	Thirumalai J;Chandramohan R;Divakar R;Mohandas E;Sekar M;Parameswaran P .Eu3+ doped gadolinium oxysulfide (Gd2O2S) nanostructures - synthesis and optical and electronic properties[J].Nanotechnology,2008(39):395703-1-395703-7-0.
[32]	LI Wenyu,LIU Yingliang,AI Pengfei,CHEN Xiaobo.Synthesis and characterization of Y_2O_2S:Eu~(3+), Mg~(2+), Ti~(4+) nanorods via a solvothermal routine[J].稀土学报（英文版）,2009(06):895-899.
[33]	Thirumalai, J.;Chandramohan, R.;Auluck, S.;Mahalingam, T.;Srikumar, S.R. .Controlled synthesis, optical and electronic properties of Eu~(3+) doped yttrium oxysulfide (Y_2O_2S) nanostructures[J].Journal of Colloid and Interface Science,2009(2):889-897.
[34]	J. Thirumalai;R. Chandramohan;T.A. Vijayan;R.M. Somasundaram .Preparation of highly ordered growth of single-crystalline Gd_2O_2S:Eu~(3+) nanostructures[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2011(2):285-291.
[35]	Ai P F;Liu Y L;Li W Y;Xiao L Y .Synthesis and characterization of Y2O2S:Eu3+,Mg2+,Ti4+ nanotubes[J].Physical Review B,2010,405(16):3360.
[36]	邝金勇,刘应亮,张静娴,袁定胜.溶剂热合成纳米球状La2O2S∶Eu3+荧光粉[J].高等学校化学学报,2005(05):822-824.
[37]	Jiang Y.;Wu Y. .Synthesis and Characterization of Nanocrystalline Lanthanide Oxysulfide via a La(OH)_3 Gel Solvothermal Route[J].Journal of the American Ceramic Society,2000(10):2628-2630.
[38]	Yu S H;Han Z H;Yang J;Zhao H Q Yang R Y Xie Y Qian Y T Zhang Y H .Synthesis and formation mechanism of La2 O2S via a novel solvothermal pressure-relief process[J].Chemistry of Materials,1999,11(02):192.
[39]	邝金勇,刘应亮,张静娴,袁定胜.溶剂热合成纳米球状La2O2S∶Eu3+荧光粉[J].高等学校化学学报,2005(05):822-824.
[40]	Luo Xixian,Cao Wanghe,Xing Mingming.Preparation of Nano Y2O2S:Eu Phosphor by Ethanol Assisted Combustion Synthesis Method[J].稀土学报（英文版）,2006(01):20-24.
[41]	Qilin Dai;Hongwei Song;Meiyuan Wang .Size and Concentration Effects on the Photoluminescence of La2O2S:Eu~(3+) Nanocrystals[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(49):19399-19404.
[42]	Zuoling Fu;Yang Geng;Hongwei Chen;Shihong Zhou;Hyun Kyoung Yang;Jung Hyun Jeong .Combustion synthesis and luminescent properties of the Eu~(3+)-doped yttrium oxysulfide nanocrystalline[J].Optical materials,2008(1):58-62.
[43]	Bang J;Abboudi M;Abrams B;Holloway P H .Combustion synthesis of Eu-,Th-and Tm-doped Ln2O2S(Ln =Y,La,Gd)phosphors[J].Journal of Luminescence,2004,106(3-4):177.
[44]	夏天,曹望和,罗昔贤,田莹.燃烧法合成Ln2O2 S：RE3+（Ln=Gd,La;RE=Eu,Tb） X射线荧光粉及发光性能[J].发光学报,2005(02):194-198.
[45]	Ozawa L .Crts are forever as video display devices[J].Materials Chemistry and Physics,1997,51(02):107.
[46]	Lo CL.;Chiou BS.;Peng CC.;Ozawa L.;Duh JG. .Synthesis of Eu3+-activated yttrium oxysulfide red phosphor by flux fusion method[J].Materials Chemistry and Physics,2001(2):179-189.
[47]	Chou TW;Mylswamy S;Liu RS;Chuang SZ .Eu substitution and particle size control Of Y2O2S for the excitation by UV light emitting diodes[J].Solid State Communications,2005(4):205-209.
[48]	The Photoluminescence Properties Of Eu~(3+),bi~(3+) Co-doped Yttrium Oxysulfide Phosphor Under Vacuum Ultraviolet Excitation[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2009(5):1183-1187.
[49]	Hyun Gyu Kim;Dong Won Hwang;Jae Sung Lee .An Undoped,Single-Phase Oxide Photocatalyst Working under Visible Light[J].Journal of the American Chemical Society,2004(29):8912-8913.
[50]	李沅英;待德昌;蔡少华 .Y2 O3:Eu,YNO4:Eu和Y2O2S:Eu的微波热合成和光致发光性能[J].光电子·激光,1995,6(09):597.
[51]	曹健,孙景志,洪剑,陈红征,汪茫.TiO2纳米带表面光伏特性的研究[J].高等学校化学学报,2003(12):2288-2289.
[52]	翟永清,刘元红,张少阳.微波场作用下La2O2S：Eu荧光粉的快速合成及其发光特性[J].发光学报,2006(06):905-909.
[53]	Li Y Y;D D C;Cai S H .Synthesis of Y2 O2 S:Eu3+ phosphor by microwave thermal effect and its luminescent properties[J].Journal of Rare Earths,1996,14(01):16.
[54]	张先如,徐政.微波技术在材料化学中的原理及其应用进展[J].辐射研究与辐射工艺学报,2005(04):196-200.
[55]	Thostenson E.T.;Chou T.-W. .Microwave processing:fundamentals and applications[J].Composites, Part A. Applied science and manufacturing,1999(9):1055-1071.
[56]	Andreas Greiner;Joachim H. Wendorff .Electrospinning: A Fascinating Method for the Preparation of Ultrathin Fibers[J].Angewandte Chemie,2007(30):5670-5703.
[57]	Koski A;Yim K;Shivkumar S .Effect of molecular weight on fibrous PVA produced by electrospinning[J].Materials Letters,2004,58(3-4):493.
[58]	Guo C F;Luan L;Chen C H;Huang D X Su Q .Preparation of Y2O2S:Eu3+ phosphors by a novel decomposition method[J].Materials Letters,2008,62(4-5):600.
[59]	Fei Zhao;Mei Yuan;Wen Zhang .Monodisperse Lanthanide Oxysulfide Nanocrystals[J].Journal of the American Chemical Society,2006(36):11758-11759.
[60]	Xi-xian Luo;Wang-he Cao;Ying Tian .Characteristic and synthesis mechanism of Gd_2O_2S:Tb phosphors prepared by cold isostatic press pretreatment[J].Optical materials,2007(2):351-356.
[61]	罗昔贤;曹望和 .稀土离子激活的稀土硫氧化物的蓝、绿、红上转换发光与谱特性[J].中国科学B辑,2002,37(02):148.
[62]	Lian J B;Sun X D;Li J G;Li X D .Synthesis,characterization and photolumineacence properties of(Gd0 99,Pr0 01)2O2S submicrophosphor by homogeneous precipitation method[J].Optical Materials,2011,33(04):596.
[63]	Liu Z G;Sun X D;Xu S K;Lian J B Li X D Xiu Z M Li Q Huo D Li J G .Th3 +-and Eu3 +-doped lanthanum oxysulfide nanocrystals gelatin-templated synthesis and luminescence properties[J].Journal of Physical Chemistry C,2008,112(07):2353.
[64]	Shiyong Zhao;Helene Roberge;Arthur Yelon .New Application of AAO Template:A Mold for Nanoring and Nanocone Arrays[J].Journal of the American Chemical Society,2006(38):12352-12353.
[65]	Jia G;Yang M;Song YH;You HP;Zhang HJ .General and Facile Method To Prepare Uniform Y2O3:Eu Hollow Microspheres[J].Crystal growth & design,2009(1):301-307.
[66]	Linfeng Gou;Cathering J. Murphy .Solution-Phase Synthesis of Cu_2O Nanocubes[J].Nano letters,2003(2):231-234.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网