以FeCl3为氧化剂,与钠基蒙脱土(MMT)以不同比例进行离子交换后所得悬浮液与吡咯(Py)单体进行气液相聚合,制备出蒙脱土/聚吡咯(MMT/PPy)复合材料.XRD、FTIR和SEM分析表明,Py单体在MMT的片层间发生了聚合反应,MMT的层间距随PPy含量增加不断变大.MMT/PPy复合材料呈现出MMT和PPy的红外特征吸收峰,但某些吸收峰出现蓝移.SEM观察显示MMT/PPy呈片状形态特征.当其中的MMT去除后,PPy仍为片状结构,与纯PPy的球粒形貌不同.电导率测试表明,MMT/PPy复合材料的电导率随PPy含量增加而提高,至40.9 wt%PPy含量时,MMT/PPy的电导率已达到PPy的电导率水平(10-1S/cm),含54.3 wt%PPy的MMT/PPy电导率甚至略高于PPy.
参考文献
[1] | Berdichevsky Y,Lo Y-H.Polypyrrole nanowire actuators[J].AdvMater,2006,18(1):122-125. |
[2] | 谢海明,韩明娟,于海英,等.聚吡咯的合成与新型双离子电池性能研究[J].高等学校化学学报,2007,28(1):109-112.Xie Haiming,Han Mingjuan,Yu Haiying,et al.Synthesis of polypyrrole and electrochemical performance of dual-ion battery[J].Chemical Journal of Chinese Universities,2007,28(1):109-112. |
[3] | Truong V-T,Riddell S Z,Muscat R F.Polypyrrole base microwave absorbers[J].J Mater Sci,1998,33(20):4971-4976 |
[4] | Armelin E,Pla R,Liesa F,et al.Corrosion protection with polyaniline and polypyrrole as anticorrosive additives for epoxy paint[J].Corros Sci,2008,50(3),721-728. |
[5] | Han Y Q,Lu Y.Preparation and characterization of graphite oxide/polypyrrole composites[J].Carbon,2007,45(12):2394-2399. |
[6] | Yap T J,Lin Q,Zhang K,et al.Preparation of SiP2polystyrene @ polypyrrole sandwich composites and hollow polypyrrole capsules with movable SiO2 spheres inside[J].J Colloid Interf Sci,2007,315(2):434-438. |
[7] | 安颢瑷,任丽,王立新,等.五氧化二钒/聚毗咯的制备及其电化学性能[J].复合材料学报,2006,23(5):58-62.An Haoyuan,Ren Li,Wang Lixin,et al.Preparation of V2O5/PPy composites and their electrochemical performance[J].Acta Materiae Compositae Sinica,2006,23(5):58-62. |
[8] | Kanatzidis M G,Tonge L M,Marks T J.In situ intercalative polymerization of pyrrole in FeOCh A new class of layered,conducting polymer-inorganic hybrid materials[J].J Am Chem Soc,1987,109(12),3797-3799. |
[9] | Faguy P W,Lucas R A,Ma W L.An FT-IR-ATR spectroscopic study of the spontaneous polymerization of pyrrole in iron-exchanged montmorillonite[J].Colloid Surface A,1995,105(1),105-112. |
[10] | Boukerma K,Piquemal J Y,Chehimi M M,et al.Synthesis and interracial properties of montmorillonite/polypyrrole nanoeomposites[J].Polymer,2006,47(2):569-576. |
[11] | Omastova M,Mravc akova M,Chodtak I,et al.Conductive polypropylene/clay/polypyrrole nanocomposites[J].Polym Eng Sci,2006,46(8):1069-1078. |
[12] | Mravc akova M,Boukerma K,Omastovtt M,et al.Montmorillonite/polypyrrole nanocomposites:The effect of organic modification of clay on the chemical and electrical properties[J].Mater Sci Eng C,2006,26(2/3):306-313. |
[13] | Khedkar S P,Radhakrishnan S.Application of dip-coating process for depositing conducting polypyrrole films[J].Thin Solid Films,1997,303(1/2):167-172. |
[14] | Kim J,Sohn D,Sung Y Y,et al.Fabrication and characterization of conductive polypyrrole thin film prepared by in situ vapor-phase polymerization[J].Synth Met,2003,132(3):309-313. |
[15] | Aequa L D,Tonin C,Varesano A,et al.Vapor phase polymerization of pyrrole on cellulose-based textile substrates[J].Synth Met,2006,156(5/6),379-386. |
[16] | Kaynak A,Najar S S,Foitzik R C.Conducting nylon,cotton and wool yarns by continuous vapor polymerization of pyrrole[J].Synth Met,2008,158(1/2),1-5. |
[17] | Wang Y B,Sotzing G A,Weiss R A.Preparation of conductive polypyrrole/polyurethane composite foams by in situ polymerization of pyrrole[J].Chem Mater,2008,20(7):2574-2582. |
[18] | Armes S P.Optimum reaction conditions for the polymerization of pyrrole by iron (Ⅲ) chloride in aqueous solution[J].Synth Met,1987,20(3):365-371. |
[19] | 江建明,戚慰先,仲蕾兰,等.化学氧化聚吡略的结构及导电性的研究[J].高分子材料科学与工程,1991,9(5):94-98.Jiang Jianming,Qi Weixian,Zhong Leilan,et al.The study on structures and conductivity of chemically oxidized polypyrrole[J].Polymeric Materials Science and Engineering,1991,9(5):94-98. |
[20] | Omastova M,Trchova M,Pointeck J,et al.Effect of polymerization conditions on the properties of polypyrrole prepared in the presence of sodium bis (2-ethylhexyl)sulfosuccinate[J].Synth Met,2004,143(2):153-161. |
[21] | Cole K C.Use of infrared spectroscopy to characterize clay intercalation and exfoliation in polymer nanocomposites[J].Macromolecules,2008,41(3):834-843. |
[22] | Manjanna J,Kozaki T,Kozai N,et aL A new method for Fe(Ⅱ)-montmorillonite preparation using Fe(Ⅱ)-nitrilotriacetate complex[J].J Nucl Sci Technol,2007,44(7):929-932. |
[23] | Pacula A,Bielafiska E,Gawel A,et al.Textural effects in powdered montmorillonite induced by freeze-drying and ultrasound pretreatment[J].Appl Clay Sei,2006,32(1/2):64-72. |
[24] | Mebrotra V,Giannelis E P.Nanometer scale multilayers of electroactive polymers:Intercalation of polypyrrole in mica-type silicates[J].Solid State Ionies,1995,51(1/2):115-122. |
[25] | Mravc akova M,Omastova M,Olejnikova K,et al.The preparation and properties of sodium and organomodifiedmontmorillonite/polypyrrole composites:A comparative study[J].Synth Met,2007,157(8/9):347-357. |
[26] | Bae W J,Kim K H,Jo W H,et aL Fully exfoliated nanoeomposite from polypyrrole graft copolymer/clay[J].Polymer,2005,46(23):10085-10091. |
[27] | Xu L B,Chen W,Mulchandani A,et al.Reversible conversion of conducting polymer films from superhydrophobic to superhydrophilic[J].Angew Chem Int Ed,2005,44(37):6009-6012. |
[28] | Ranaweera A U,Bandara H M N,Rajapakse R M G.Electronically conducting montmorillonite-Cu2S and montmorillonite-Cu2S-polypyrrole nanoeomposites[J].Electrochimica Acta,2007,52(25):7203-7209. |
[29] | Omastova M,Boukerma K,Chehimi M M,et al Novel silicon carbide/polypyrrole composites:Preparation and physieochemical properties[J].Mater Res Bull,2005,40(5):749-765. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%