基于TGA-FTIR联用技术,研究一种高灰分、低热值城市生活垃圾与秸秆(棉秆及玉米秆)在不同质量配比下混合热解过程中气态硫和氯的析出特性.结果表明,城市生活垃圾掺加秸秆后,促进垃圾的热解,CH4及有机物析出增加;随着秸秆掺加比例提高,H2S及SO2的析出量增加,HC1起始析出温度有所降低,但析出量减小.试验结果为城市生活垃圾及秸秆的综合利用提供理论依据.
参考文献
[1] | Loay Saeed;Antti Tohka;Matti Haapala;Ron Zevenhoven .Pyrolysis and combustion of PVC,PVC-wood and PVC-coal mixtures in a two-stage fluidized bed process[J].Fuel Processing Technology,2004(14):1565-1583. |
[2] | L.Sorum;M.G.Gronli;J.E.Hustad .Pyrolysis characteristics and kinetics of municipal solid wastes[J].Fuel,2001(9):1217-1227. |
[3] | Changkook Ryu;Vida N. Sharifi;Jim Swithenbank .Waste pyrolysis and generation of storable char[J].International journal of energy research,2007(1):177-191. |
[4] | Anton R. Reed;Paul T. Williams .Thermal processing of biomass natural fibre wastes by pyrolysis[J].International journal of energy research,2004(2):131-145. |
[5] | H.M. Zhu;J.H. Yan;X.G. Jiang;Y.E. Lai;K.F. Cen .Study on pyrolysis of typical medical waste materials by using TG-FTIR analysis[J].Journal of hazardous materials,2008(1/2):670-676. |
[6] | 王树荣,刘倩,郑赟,文丽华,骆仲泱,岑可法.基于热重红外联用分析的生物质热裂解机理研究[J].工程热物理学报,2006(02):351-353. |
[7] | 王爽,王宁,于立军,姜秀民,李祯,何培民.海藻的热解特性分析[J].中国电机工程学报,2007(14):102-106. |
[8] | Nakorn Worasuwannarak;Taro Sonobe;Wiwut Tanthapanichakoon .Pyrolysis behaviors of rice straw, rice husk, and corncob by TG-MS technique[J].Journal of analytical & applied pyrolysis,2007(2):265-271. |
[9] | Eigenmann F;Maciejewski A;Baiker A .Quantitative calibration of spectroscopic signals in combined TG-FTIR system[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2006(1):81-92. |
[10] | Zhu H M;Jiang X G;Yan J H et al.TG-FTIR Analysis of PVC Thermal Degradation and HC1 Removal[J].Journal of Analytical and Applied Pyrolysis,2008,82(01):1-9. |
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