欢迎登录材料期刊网

材料期刊网

高级检索

用DSC和TBA两种方法测定了苯乙烯-丙烯腈-N-苯基马来酰亚胺乳液共聚物的玻璃化温度Tg,研究了共聚物的流变性能,测定了共聚物的熔体流动指数n,发现共聚物的熔体流动指数越大,两种方法测定的共聚物的Tg的差值越大。

The glass transition temperature of styrene-acrylonitrile-N-phenyl-maleimide emulsion copolymer was determined by DSC and TBA method. The terpolymer′s rheological property and flow index n were studied. The result shows that Tg increases with the increasing PMI content while TgTBA and TgDSC of terpolymers showed different tends. The rheological studies show that TgTBA-TgDSC increases with the increasing of the terpolymer′s flow index.

参考文献

[1] Barrales-rienda J M;Gonzalez J I;De La Campa et al.[J].Journal of Macromolecular Science:Chemistry,1977,A11(02):267-286.
[2] 牧野吉夫 .[P].日本公开特许公报,JP 平 3-39347,1991.
[3] Kessenikh R M;Petrov A V .[J].Soedin Ser B,1969,11(07):481.
[4] 台会文,杜淼,刘天昌,张留成.苯乙烯-丙烯腈-N-苯基马来酰亚胺乳液共聚物的热分析表征[J].高分子材料科学与工程,1997(03):62-66.
[5] 松永藤尚;福原浩;小林正夫 .[P].日本公开特许公报,JP 昭62-273952,1987.
[6] Yuan Y.;Narkis M.;Bell JP.;Siegmann A. .EMULSION COPOLYMERIZATION OF N-PHENYLMALEIMIDE WITH STYRENE[J].Journal of Applied Polymer Science,1996(6):1049-1054.
[7] Shultz A R;Gendron B M .[J].Journal of Macromolecular Science:Chemistry,1974,A8:175.
[8] Chang Dae Han.Rheologh in Polymer Processing[M].New York:Academic Press Inc,1976:106-109.
[9] 何曼君;陈维孝;董西侠.高分子物理[M].上海:复旦大学出版社,1990
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%