利用同时析晶的方法,通过调整云母和β-锂辉石两者的含量可得到具有可加工性、低膨胀系数的复合材料,可应用在牙科材料中.采用差热分析(DTA)、X衍射分析(XRD)、扫描电镜(SEM)等分析手段对该系统微晶玻璃析晶过程及微观结构进行研究,根据差热分析确定热处理工艺控制理想晶相的析出,这是得到理想性能复合材料的关键.其中β-锂辉石成分有增强基体硬度的作用,但是当它的含量超过50%时就会削弱基体的可加工性能,通过调整β-锂辉石的含量最终得到膨胀系数<40×10-1/℃,而且具有优良加工性能的材料.
参考文献
[1] | Stavffer R N .Now:a glass-ceramic that's machinable[J].Manufacturing Engineering,1979,2(03):26. |
[2] | Yamamoto T;Takamizu M;Kohno A .Influence of residual surface investment material on cry-stallization shrinkage of a mica2 based glass-ceramic[J].Dental Materials,2002,5(18):336. |
[3] | Yu B;Liang K;Gu S .Effect of the microstructure on the mechanical properties of CaO-P2O5-SiO2-MgO-F-glass ceramics[J].Ceramics International,2003,29(06):695-698. |
[4] | Goswami M;Sarkar A;Mirza T et al.Study of some thermal and mechanical properties of magnesium aluminium silicate glass ceramic[J].Ceramics International,2002,28(06):585-592. |
[5] | Ibrahim D;El-Meliegy E .Mica leucite dental porcelain[J].British Ceramic Transactions,2001,100(06):260-264. |
[6] | Emad A. A. Mustafa .Fluorophlogopite porcelain based on talc-feldspar mixture[J].Ceramics International,2001(1):9-14. |
[7] | Hoche T.;Khodos II.;Habelitz S. .Origin of unusual fluorophlogopite morphology in mica glass-ceramics of the system SiO2-Al2O3-MgO-K2O-Na2O-F-2[J].Journal of Crystal Growth,1998(1/2):185-195. |
[8] | Chen X F;Hench L;Greenspan D et al.Investigation on phase separation,nucleation and crystallization in bioactive glass-ceramics containing fluorophlogopite and fluorapatite[J].Ceramics International,1998,24(05):401-410. |
[9] | Wang M;Wu N;Yang S et al.Morphology and microstructure in the sintering of spodum-ene precursor powders with TiO2 additive[J].European Ceramic Society,2003,23(03):437-443. |
[10] | Suzdal'tsev E .Glass ceramics of spodumene composition with controlled dielectric constant[J].Refractories and Industrial Ceramics,2002,43(06):176-178. |
[11] | Taruta S;Hayashi T;Kitajiman K .Preparation of Machinable Cordierite/mica Composite by Low temperature Sintering[J].Journal of the European Ceramic Society,2004,24:3149. |
[12] | Taruta S;Yonekura H;Suzuki S S et al.Sintering and ContactDamage of Spinel/mica Comp-osites Prepared from Alumina,Magnesia and Mica composition Glass PowderMixtures[J].Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi / Journal of the Ceramic Society of Japan,2002,110:208. |
[13] | 张明华,叶军,邹宏恩,唐农轩,蔡和平.微孔涂层植人物与骨组织界面的生物力学关系[J].第四军医大学学报,1999(12):1081-1084. |
[14] | 蒋晓曙,隋普辉,陆雷.热处理制度对LZAS玻璃陶瓷析晶和显微结构的影响[J].硅酸盐通报,2009(04):779-783. |
[15] | 陈伟民;陈楷;陈扬枝 .K2O-MgO-SiO2-CaF2微晶玻璃的晶相演变规律[J].无机材料学报,1998,13(05):725-728. |
[16] | 董伟霞,包启富,顾幸勇.锂辉石对Ca-B-Al-Si体系复合材料性能的影响[J].硅酸盐通报,2009(04):818-823. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%