通过氙灯辐照试验对ARMOS纤维进行了紫外老化试验,采用单丝拉伸、FTIR、SEM和XRD研究了紫外光辐照对ARMOS纤维的影响.结果表明,短时间的紫外光辐照引起ARMOS纤维的拉伸强度在辐照6 h后上升了13.7%,36 h后又下降了2.1%.利用FTIR、SEM和XRD发现,经过紫外光辐照后,ARMOS纤维中酰胺基团的C-N键发生了断裂,同时氢键缔合能力增强,纤维结晶度增加,从而导致纤维表面出现沟槽,断口方式由微纤劈裂转向脆性断裂,说明短时间的紫外辐照对ARMOS纤维有削弱和强化2种相互矛盾的影响作用.
参考文献
| [1] | 赵克熙.原苏联芳纶复合材料研究进展及其在固体发动机壳体上的应用[J].宇航材料工艺,1995,25(5):8-19.Zhao Kexi.Research progress of the aramid composite in the former USSR and it used in solid rocket motor case[J].Aerospace Materials ＆ Technology,1995,25(5):8-19. |
| [2] | Perepelkin K E,等.俄罗斯高性能纤维Armos与其他类型对位芳族聚酰胺纤维的比较[J].骆为林,译.国外纺织技术,2000,180(3):19-22.Perepelkin K E,et al.Compare Russia high performance Armos with other style pars aromatic copolyamide fiber[J].Luo Weilin,trans.Foreign Weave Technology,2000,180(3):19-22. |
| [3] | 孙友德,刘庆备.俄罗斯杂环芳纶--概况与发展(一)[J].高科技纤维与应用,2004,29(1):8-10.Sun Youde,Liu Qingbei.Russia heterocyclic coptrolyaramids (1) General condition and development[J].Hi-Tech Fiber ＆ Application,2004,29(1):8-10. |
| [4] | 于春茂,于国柱,魏月贞,龙军.APMOC-Ⅲ纤维组成结构与结晶的研究[J].合成纤维工业,2000,23(1):45-48.Yu Chunmao,Yu Guozhu,Wei Yuezhen,Long Jun.The study of component and crystallinity[J].China Synthetic Fiber Industry,2000,23(1):45-48. |
| [5] | 沃西源,涂彬,夏英伟.芳纶纤维及其复合材料件能与应用研究[J].航天返回与遥感,2005,26(2):50-55.Wo Xiyuan,Tu Bin,Xia Yingwei.The properties and application of aramid fibers and the composite materials[J].Spacecraft Recovery ＆ Remote Sensing,2005,26 (2):50-55. |
| [6] | Perepelkin K E,Andreeva I V,Pakshver E A,Morgoeva I Y.Thermal characteristics of pars-aramid fibres[J].Fibre Chemistry,2003,35(4):265-269. |
| [7] | Bourbigot S,Flambard X,Poutch F.Study of the thermal degradation of high performance fibres--Application to polybenzazole and p-aramid fibres[J].Polymer Degradation and Stability,2001,74(2):283-290. |
| [8] | Tamargo-Martinez K,Villar-Rodil S,Paredes J I,Martinez-Alonso A,Tascon J M D.Studies on the thermal degradation of poly (p-phenylene benzobisoxazole)[J].Chem Mater,2003,15:4052-4059. |
| [9] | 蔡敬刚,樊虎,李铁.C对芳纶和锦纶材料降解性能的影响[J].产业用纺织品,2006,194(11):12-16.Cai Jinggang,Fan Hu,Li Tie.The fluence of humidity on degradability of polyamide fiber and poly-phenylene terephthalamide fiber materials[J].Industry Drygoods,2006,194(11):12-16. |
| [10] | 迟倩萍,韩丽华,张淑萍.Armos/环氧FRP模压板耐库存和湿热性能的研究[J].纤维复合材料,2003,20(2):40-41.Chi Qianping,Han Lihua,Zhang Shuping.Study on the antiaging and hygrothermal properties of Armos/epoxy molded plates[J].Fiber Composite,2003,20(2):40-41. |
| [11] | 刘晓艳.柔性高性能纤维的光热稳定性研究[D].上海:东华大学,2005:66-84.Liu Xiaoyan.Study on the durability and stability of flexible high performance fibers in thermal and light radiation[D].Shanghai:Donghua University,2005,66-84. |
| [12] | Zhang Huapeng,Zhang Jianchun,Chen Jianyong,et al.Effects of solar UV irradiation on the tensile properties and structure of PPTA fiber[J].Polymer Degradation and Stability,2006,91:2761-2767. |
| [13] | 斯奎.PBO纤维的耐热性和耐紫外光特性的研究[D].西安:西北工业大学,2006:54-57.Si Kui.Study on the heat-resistant and resistance to ultraviolet radiation of PBO fiber[D].Xi'an:Northwest Polytechnical University,2006:54-57. |
| [14] | 赵瑶兴,孙祥玉.有机分子结构光谱鉴定[M].北京:科学出版社,2003:20-60.Zhao Yaoxing,Sun Xiangyu.Spectrum identification of organic molecular structure[M].Beijing:Science Press,2003:20-60. |
| [15] | 翁诗甫.傅里叶变换红外光谱仪[M].北京:化学工业出版社,2005:320-326.Weng Shifu.Fourier transform infrared spectrometer[M].Beijing:Chemical Industry Press,2005:320-326. |
| [16] | Rap Y,Waddon A J,Farris R J.The evolution of structure and properties in poly(p-phenylene terephthalamide) fibers[J].Polymer,2001,42:5925-5935. |
| [17] | Downing J W,Newell J.Characterization of structural changes in thermally enhanced Kevlar-29 fiber[J].Journal of Applied Polymer Science,2004,91(1):417-424. |
| [18] | Bernstein R,Derzon D K,Gillen K T.Kevlar degradation studies[J].Polymer Preprints,2003,44(2):952-967. |
| [19] | Brown J R,Browne N M,Burchill P J,Egglestone G T.Photochemical ageing of Kevlar-49[J].Textile Research Journal,1083,53(4):214-219. |
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