本文提出了一个钝化金属电极系统恒电位阶跃条件下的线性模型,并据此模型,分析了钝化体系恒电位阶跃条件下的暂态响应过程,给出了一套解析反映钝化膜的生长与溶解性质的电化学参数的方法。该方法比交流阻抗能更加简便快速地测得同样的电化学参数。
The transient response of passivated metallic electrode system under potential step is analysed with the aid of a linear model, and a technique for calculating the parameters characterizing the growth and dissolution of passive film is proposed. It is believed that the information which is expected from impedance measurement can be obtained by this technique and that this technique is superior to the former as it is much more rapid.
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