以改性丙烯酸酯类乳液为成膜物质,聚磷酸铵、季戊四醇、三聚氰胺为膨胀阻燃体系,并添加可膨胀石墨、硫酸镁晶须进行改性,制备水性超薄膨胀型钢结构防火涂料.采用垂直燃烧法、热重分析(TGA)、扫描电镜(SEM)、X射线衍射(XRD)等方法研究了防火涂层的结构与耐火性能,结果表明,以硅丙乳液和环氧改性丙烯酸酯乳液复配为成膜物质,受火膨胀后防火涂层形成了致密的“蜂窝”状结构,获得较好的防火性能.钛白粉在高温中能转变成焦磷酸钛,对提高防火性能起到积极的作用.添加可膨胀石墨和晶须具有明显的协效阻燃效果.3%可膨胀石墨和3%硫酸镁晶须共同改性的防火涂层在800℃的残余质量为36%.
参考文献
[1] | 时虎.超薄型钢结构防火涂料研究[J].中国涂料,2005(04):24-27. |
[2] | Andrea M. Pereyra;Guadalupe Canosa;Carlos A. Giudice .Nanostructured Protective Coating Systems, Fireproof and Environmentally Friendly, Suitable for the Protection of Metallic Substrates[J].Industrial & Engineering Chemistry Research,2010(6):2740-2746. |
[3] | Wang, GJ;Yang, JY .Influences of binder on fire protection and anticorrosion properties of intumescent fire resistive coating for steel structure[J].Surface & Coatings Technology,2010(8):1186-1192. |
[4] | R. Otdhal;D. Vesely;J. Nasadova .Intumescent coatings based on an organic-inorganic hybrid resin and the effect of mineral fibres on fire-resistant properties of intumescent coatings[J].Pigment & Resin Technology,2011(4):247-253. |
[5] | 陈中华,李崇裔.水性超薄型钢结构防火涂料的研制与性能研究[J].涂料工业,2011(04):26-30. |
[6] | Wang ZY;Han EH;Ke W .An investigation into fire protection and water resistance of intumescent nano-coatings[J].Surface & Coatings Technology,2006(3/4):1528-1535. |
[7] | Zhenyu Wang;Enhou Han;Wei Ke .Influence of expandable graphite on fire resistance and water resistance of flame-retardant coatings[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2007(5):2237-2253. |
[8] | Bodzay, B.;Bocz, K.;Bárkai, Z.;Marosi, G. .Influence of rheological additives on char formation and fire resistance of intumescent coatings[J].Polymer Degradation and Stability,2011(3):355-362. |
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