本文以扫描电镜(带X射线波长谱仪)为主要工具,对Fe-23Cr-6Al合金(不含稀土及加La,Ce和Y)1300℃高温氧化进行了研究.阐明了不含稀土合金氧化皮粘附性极差的根源,是部分向外扩散的阳离子留在氧化皮/基体界面处的空位聚集成空腔,使氧化皮和基体产生部分脱离的缘故.并认为添加稀土改变氧化皮的生长机制,是稀土改善Fe-Cr-Al合金高温氧化皮粘附性的主要原因.
High temperature oxidation of Fe-23Cr-6Al alloys with and without La, Ceand Y additions at 1300℃ in air has been studied using SEM with a wavelengthdispersive X-ray spectrometer. It is shown that the presence of the cavities formedby the condensation of vacancies caused by the outward diffusion cations resultsin a local detachment at the oxide/substrate interface. This may mainly be respon-sible for the poor oxide adhesion of the alloy without RE. The addition of REchanges the mechanism of growth of the oxide, thus accounts for the improve-ments in oxide adhesion.
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