采用机械球磨晶态Ti3Ni2 (Ti2Ni/TiNi)合金的方法制备非晶态的Ti3Ni2合金,并研究其电化学性能.充放电测试结果显示,非晶态Ti3Ni2合金成功地解决了晶态Ti3Ni2合金在高温下(333 K)循环寿命极短的缺点.在333K循环19次后,相对于晶态Ti3Ni2合金较低的容量保持率(39.47％),其非晶态合金有效的将容量保持率提高到88.83％.通过Tafel极化,线性极化以及交流阻抗测试,发现这种改善源于非晶态Ti3Ni2合金的耐蚀性远优于其晶态合金.
参考文献
| [1] | Santos D M F;Sequeria C A C;Lobo R F M .[J].International Journal of Hydrogen Energy,2010,35(18):9901. |
| [2] | 金航军,张金龙,孟祥海,林根文,葛建生.TiV0.8-xCr1.2Alx合金的结构与贮氢性能[J].稀有金属材料与工程,2008(05):803-807. |
| [3] | Raju M;Ananth M V;Vijayaraghavan L .[J].Journal of Power Sources,2008,180(02):830. |
| [4] | 王大辉,吴彦军,阎汝煦,罗永春,康龙.Al替代Mg对La2MgNi7.5Al1.5贮氢合金相结构和电化学性能的影响[J].稀有金属材料与工程,2008(01):45-49. |
| [5] | Yu X B;Feng S L;Wu Z et al.[J].Journal of Alloys and Compounds,2005,393:129. |
| [6] | Abea M;Kujib T et al.[J].Journal of Alloys and Compounds,2007,446-447:200. |
| [7] | 刘守平,田卫国,刘志红,刘小军.贮氢合金V3TiNi0.56Mx耐腐蚀性能研究[J].稀有金属材料与工程,2009(01):15-18. |
| [8] | Takeshita H.T.;Tanaka H. .Hydrogenation characteristics of ternary alloys containing Ti_4Ni_2X (X=O, N, C)[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(2):188-193. |
| [9] | Luan B;Cui N;Liu H K et al.[J].Journal of Power Sources,1995,55(02):197. |
| [10] | Liu J;Gao X P;Song D Y et al.[J].Journal of Alloys and Compounds,1995,231:852. |
| [11] | Zhao X Y;Ma L Q;Ding Y et al.[J].Intermetallics,2010,18(05):1086. |
| [12] | Luan B;Cui N;Zhao H et al.[J].Journal of Power Sources,1995,55:101. |
| [13] | Wakao S;Yonemura Y;Nakano H et al.[J].Journal of the Less-Common Metals,1984,104:365. |
| [14] | 徐艳辉;陈长聘;王启东 .[J].稀有材料金属与工程,2001,30(01):23. |
| [15] | Xu Y H;Chen C P;Wang Q D et al.[J].International Journal of Hydrogen Energy,2001,26:1177. |
| [16] | Xu Y H;Chen C P;Wang Q D et al.[J].Journal of Chemical Physics,2001,71:190. |
| [17] | Xu Y H;Chen C P;Wang Q D et al.[J].Journal of Power Sources,2002,112:105. |
| [18] | Luborsky F E.Amorphous Metallic Alloys[M].London:Butterworth and Co.Ltd,1983 |
| [19] | Zheng G.;White RE.;Popov BN. .APPLICATION OF POROUS ELECTRODE THEORY ON METAL HYDRIDE ELECTRODES IN ALKALINE SOLUTION[J].Journal of the Electrochemical Society,1996(2):435-441. |
| [20] | Ratnakumar BV.;Bowman RC.;Hightower A.;Fultz B.;Witham C. .ELECTROCHEMICAL STUDIES ON LANI5-XSNX METAL HYDRIDE ALLOYS[J].Journal of the Electrochemical Society,1996(8):2578-2584. |
| [21] | Rongeat C;Roué L .[J].Journal of Power Sources,2004,132:302. |
| [22] | Zhao X Y;Ma L Q;Qu X X et al.[J].Energy and Fuels,2009,23:4678. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%