粒径为20—30nm的α—Fe粒子由CWCO2激光气相热解Fe(CO);方法制备.对α一Fe纳米粒子从室温到高温的氧化研究表明,在低于150℃条件下,氧化产物为Fe3O4;200-300℃则为γ—Fe2O3;高于400℃,γ—Fe2O3转变为α—Fe2O3.高温氧化过程中无Fe3O4和FeO(浮氏体)形成用TEM和XRD分析表明,α—Fe纳米粒子氧化产物γ一Fe2O3及α一Fe2O3仍为纳米微粒,而且具有实心和空心两种形态本文还探讨了氧化物的形成机制.
An extensive study has been made of the oxidation of the α-Fe nano-particles nm)prepared by CW CO2 Laser-induced pyrolysis of Fe(CO),.It has been indicated that the surface oxide formed on the α-Fe nano-particles at room temperature in air is Fe3O4.The α
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