PBI及衍生物的合成及其溶解性能研究

材料导报, 2009, 23(6): 21-24.

PBI及衍生物的合成及其溶解性能研究

唐艳芳 ^1, , 王彪 ^2, , 陆仙娟 ^3, , 王华平 ^4, , 朱方亮 ^5,

1.东华大学纤维材料改性国家重点实验室,上海,201620

2.东华大学纤维材料改性国家重点实验室,上海,201620

3.东华大学纤维材料改性国家重点实验室,上海,201620

4.东华大学纤维材料改性国家重点实验室,上海,201620

5.东华大学纤维材料改性国家重点实验室,上海,201620

基金项目: 上海市重点学科建设项目(13603)

关键词：聚苯并咪唑 , 聚(2,5-苯并咪唑) , 缩聚反应 , 溶解性

Study on the Synthesis and Solubility of Polybenzimidazole and Derivatives

由间苯二甲酸(II)A)和3,3',4,4'-二氨基联苯胺(TAB)采用逐步升温溶液缩聚的方法合成了聚苯并味唑(PBI),并通过FT-IR、1H-NMR和TGA等对其进行了表征,讨论了聚合过程中的影响因素,优化了聚合条件,同时还比较了PBI和聚(2,5-苯并咪唑)(ABPBI)在不同溶荆中的溶解性能.

参考文献

[1]	Brinker K C;Robinson I M .Polybenzimidazoles[P].US,2895948,1959-07-21.
[2]	Vogel H;Marvel C S .Polybenzimidazoles,new thermally stable polymers[J].Polymer Science,1961,50:511.
[3]	Vogel H;Marvel C S .Cross-linked polybenzimidazole mem brane for gas separation[J].Polymer Science,1963,A1:1531.
[4]	Chung T S .A critical review of polybenzimidazoles.Historical development and future R＆D[J].Polym Rew,1997,37(02):277.
[5]	Asensio J A;Borr6s S;Gómez-Romeroa P .Sulfonated poly(2,5-benzimidazole) (SABPBI) impregnated with phosphoric acid as proton conducting membranes for polymer electrolyte fuel cells[J].Electrochimica Acta,2004,49:4461.
[6]	He RH;Li QF;Bach A;Jensen JO;Bjerrum NJ .Physicochemical properties of phosphoric acid doped polybenzimidazole membranes for fuel cells[J].Journal of Membrane Science,2006(1/2):38-45.
[7]	金俊弘,李光,江建明.聚苯撑苯并二噁唑（PBO）的合成[J].东华大学学报(自然科学版),2002(06):122-125.
[8]	Asensio J A;Borrós S;Gómez-Romero P .Enhanced conductivity in polyanion-containing polybenzimidazoles.Improved materials for proton-exchange membranes and PEM fuel cells[J].Electrochemistry Communications,2003,5:967.
[9]	Lobato J;Canizares P;Rodrigo MA;Linares JJ;Aguilar JA .Improved polybenzimidazole films for H3PO4-doped PBI-based high temperature PEMFC[J].Journal of Membrane Science,2007(1/2):47-55.
[10]	John R.Klaehn;Thomas A.Luther;Christopher J.Orme .Soluble N-Substituted Organosilane Polybenzimidazoles[J].Macromolecules,2007(21):7487-7492.
[11]	Zhang H F .Novel phosphoric acid doped polybenzimizole membranes for fuel cells[D].NY.Rensselaer Polytechnic Institute,2004.
[12]	Asensio JA.;Borros S.;Gomez-Romero P. .Proton-conducting polymers based on benzimidazoles and sulfonated benzimidazoles[J].Journal of Polymer Science, Part A. Polymer Chemistry,2002(21):3703-3710.
[13]	Shogbon CB;Brousseau JL;Zhang HF;Benicewicz BC;Akpalu YA .Determination of the molecular parameters and studies of the chain conformation of polybenzimidazole in DMAc/LiCl[J].Macromolecules,2006(26):9409-9418.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

PBI及衍生物的合成及其溶解性能研究

Study on the Synthesis and Solubility of Polybenzimidazole and Derivatives

参考文献