以氢气稀释的硅烷和氢气为反应气体,利用PECVD法先在玻璃衬底上生长非晶硅薄膜,然后利用磁控溅射法在非晶硅薄膜上镀制铝膜,最后将镀有铝膜的非晶硅薄膜样品置于快速热处理炉中,在外加电场辅助条件下,在氮气气氛下对薄膜样品进行退火制备多晶硅薄膜.本论文研究了不同外加电场强度和退火时间对非晶硅薄膜晶化的影响.利用XRD、SEM和Raman等测试方法对薄膜样品的晶相结构、表面形貌和晶化程度进行了表征.实验结果表明,在外加横向电场辅助铝诱导晶化的条件下,非晶硅薄膜在500 ℃低温下成功地转化成多晶硅薄膜,并且随着横向电场强度的增大以及退火时间的延长,薄膜的晶化程度增强,晶粒尺寸增大.
参考文献
[1] | Koch C.;Schubert M.;Ito M. .Low-temperature deposition of amorphous silicon solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(2):227-236. |
[2] | Beaucarne G.;Bourdais S.;Slaoui A.;Poortmans J. .Thin-film polysilicon solar cells on foreign substrates using direct thermal CVD: material and solar cell design[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2002(0):229-237. |
[3] | Staebler D L;Wronski C R .Reversible Conductivity Changes in Discharge-produced Amorphous Silicon[J].Applied Physics Letters,1977,31(04):292-294. |
[4] | J. P. Lu;K. Van Schuylenbergh;J. Ho;Y. Wang;J. B. Boyce;R. A. Street .Flat panel imagers with pixel level amplifiers based on polycrystalline silicon thin-film transistor technology[J].Applied physics letters,2002(24):4656-4658. |
[5] | Oliver N;Stephan B;Stephen P et al.Aluminum-induced Crystallization of Silicon on Glass for Thin-film Solar Cells[J].Solar Energy Materials and Solar Cells,2001,65:385-392. |
[6] | Lim DG.;Jang DM.;Yi JS. .A novel multicrystalline silicon solar cell using grain boundary etching treatment and transparent conducting oxide[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(1/4):571-578. |
[7] | 陈城钊,方健文,林璇英.a-Si∶H 薄膜固相晶化法制备多晶硅薄膜[J].浙江师范大学学报(自然科学版),2002(03):246-249. |
[8] | 王红娟,卢景霄,刘萍,王生钊,张宇翔,张丽伟,陈永生.低温快速热退火晶化制备多晶硅薄膜[J].可再生能源,2006(03):13-15. |
[9] | 陈永生,卢景霄,张宇翔,王生钊,杨仕娥,郜小勇,李秀瑞.非晶硅薄膜的快速热退火机理研究[J].人工晶体学报,2006(05):1137-1140,1074. |
[10] | Oliver Nast;Andreas J. Hartmann .Influence of interface and Al structure on layer exchange during aluminum-induced crystallization of amorphous silicon[J].Journal of Applied Physics,2000(2):716-724. |
[11] | 罗士雨,冯磊,汪洪,林辉,滕浩,黄涛华,周圣明.非晶硅薄膜制备及其晶化特性研究[J].人工晶体学报,2008(05):1191-1194. |
[12] | Song K S;Lee J B;Jun S I et al.Polycrystalline Thin Film Transistors Fabricated by FALC(Field Aided Lateral Crystallization) Technique[J].Journal of Materials Science Letters,2003,18(15):1209-1211. |
[13] | Park S H;Jun S I;Song K S et al.Field Aided Lateral Crystallization of Amorphous Silicon Thin Film[J].Japanese Journal of Applied Physics,1999,38(2A):108-109. |
[14] | Haque MS.;Brown WD.;Naseem HA. .ALUMINUM-INDUCED CRYSTALLIZATION AND COUNTER-DOPING OF PHOSPHOROUS-DOPED HYDROGENATED AMORPHOUS SILICON AT LOW TEMPERATURES[J].Journal of Applied Physics,1996(10):7529-7536. |
[15] | 陈一匡,林揆训,罗志,梁锐生,周甫方.铝诱导非晶硅薄膜的场致低温快速晶化及其结构表征[J].物理学报,2004(02):582-586. |
[16] | 蔡捷宏,姚若河,陈明鑫,许佳雄,陈岳政.金属诱导法制备多晶硅薄膜的研究进展[J].轻金属,2006(11):48-50. |
[17] | J. B. Boyce;R. T. Fulks;J. Ho;R. Lau;J. P. Lu;P. Mei;R. A. Street;K. F. Van Schuylenbergh;Y. Wang .Laser processing of amorphous silicon for large-area polysilicon imagers[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2001(1/2):137-142. |
[18] | Hsu C M;Chen I F;Yu M C .Stress Effect of Aluminum-induced Crystallization of Sputtered Amorphous Silicon Thin Films[J].Japanese Journal of Applied Physics,2003,42:4928-4934. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%