以铁损来判断热浸镀锌的温度对镀锌层的影响,结果欠准;硅元素对镀锌存在sandelin效应.这2种因素对锌镀层的生长、质量及性能都有重大的影响,且都难以控制.为此,以工业纯铁和Fe-0.1Si(0.1%,质量分数)合金薄片为热镀锌基材,探讨锌液温度和钢中硅元素对镀层生长和镀层组织的影响.利用扫描电镜对2种基材在450~530℃内的热镀锌层厚度及其组织进行了测量与分析.结果表明:工业纯铁在480 ℃下热镀锌时镀层生长最快,Fe-0.1 Si合金在470℃热镀锌时镀层生长最快;在镀层生长最快的温度下,2种基材的镀层特征具有相似性;当镀锌温度超过500℃时,工业纯铁和Fe-0.1Si合金镀层中的ζ相消失,镀层由δ相组成.
参考文献
[1] | Horstmann D;Peters F K.The reaction between iron and zinc[A].London:Zinc Development Association,1971:75 -79. |
[2] | Mackowiak J;Short N R .Metallurgy of galvanized coatings[J].Inter Metals Reviews,1979,24(01):1- 19. |
[3] | Verma A R B;Van-Ooij W J .High-temperature batch hotdip galvanizing,Part 2.Comparison of coatings formed in the temperature range 520 ~550℃[J].Surface and Coatings Technology,1997,89(1/2):143 - 150. |
[4] | Pelerian J;Hoffmann J;Leroy V .The influence of silicon and phosphorus on the commercial galvanization of mild steels[J].Metallwissenschaft und Technik,1981,35(09):870 - 873. |
[5] | 李智,尹付成,彭梅香,贺跃辉.硅对热浸锌镀层的影响[J].湘潭大学自然科学学报,2004(01):81-84. |
[6] | Sandelin R W .Galvanizing characteristics of different types of steel[J].Wire and Wire Products,1941,16(01):28-35. |
[7] | Hong J H;Oh S J;Kwon S J .Mossbaner analysis of the iron-zinc intermetallic phases[J].Intermetallics,2003,11(03):207 -213. |
[8] | Giorgi ML;Durighello P;Nicolle R;Guillot JB .Dissolution kinetics of iron in liquid zinc[J].Journal of Materials Science,2004(18):5803-5808. |
[9] | Wang J H;Su X P;Yin F C et al.The 480 ℃ and 405 ℃ isothermal section of the phase diagram of Fe-Zn-Si ternary system[J].Journal Alloys and Compounds,2005,399(1/2):214 -218. |
[10] | X. Su;F. Yin;Z. Li .Thermodynamic calculation of the Fe-Zn-Si system[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2005(1/2):156-163. |
[11] | Horatmann D.Formation and growth of iron-zinc alloy layers[A].London:Zinc Development Association,1986:289 - 296. |
[12] | Habrakem L.Contribution to a scientific explanation of the metallurgical phenomena occurring in the iron-zinc reaction[A].London:Zinc Development Association,1979:121-123. |
[13] | XUPING SU;NAI-VONG TANG;JIM M. TOGURI .450 deg C ISOTHERMAL SECTION OF THE Fe-Zn-Si TERNARY PHASE DIAGRAM[J].Canadian Metallurgical Quarterly,2001(3):377-384. |
[14] | 李金桂;吴再思.防腐蚀表面工程技术[M].北京:北京化工出版社,2003:176-178. |
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