利用正己烷制备负载型碳化钼催化剂及其加氢脱硫活性

催化学报 , 2005, 26(12): 1047-1052.

利用正己烷制备负载型碳化钼催化剂及其加氢脱硫活性

朱全力 ^1, , 赵旭涛 ^2, , 赵振兴 ^3, , 马红江 ^4, , 邓友全 ^5,

1.中国石油天然气股份有限公司兰州石化公司石油化工研究院,甘肃兰州,730060;中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州,730000

2.中国石油天然气股份有限公司兰州石化公司石油化工研究院,甘肃兰州,730060

3.中国石油天然气股份有限公司兰州石化公司石油化工研究院,甘肃兰州,730060

4.中国石油天然气股份有限公司兰州石化公司石油化工研究院,甘肃兰州,730060

5.中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州,730000

关键词：碳化钼 , 正己烷 , 碳化 , 噻吩 , 加氢脱硫

Preparation of Supported Molybdenum Carbide Catalyst Using n-Hexane and Its Hydrodesulfurization Activity

利用具有较长碳链的正己烷作为原料对氧化钼进行程序升温碳化制备碳化钼. X射线衍射、X射线光电子能谱表征和BET比表面积测定以及噻吩的加氢脱硫活性评价结果表明,正己烷作为碳化原料在600 ℃左右可对担载的氧化钼进行碳化,正己烷的使用不仅可以降低碳化所需的温度,还能在碳化过程中起到一定的改善碳化钼分散度的作用.

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利用正己烷制备负载型碳化钼催化剂及其加氢脱硫活性

Preparation of Supported Molybdenum Carbide Catalyst Using n-Hexane and Its Hydrodesulfurization Activity

参考文献