欢迎登录材料期刊网

材料期刊网

高级检索

先采用真空袋压法制备含CaCO3/环氧树脂表面功能层的玻璃纤维增强环氧树脂复合材料,再通过化学刻蚀与表面修饰,在玻璃纤维增强环氧树脂复合材料上制备出超疏水表面。采用扫描电镜和动/静态接触角分析仪,表征表面的形貌和疏水性,结果表明,在复合材料表面构建了具有微-纳米尺度二元粗糙结构;采用1%(质量分数)的硬脂酸修饰后,其表面与水的接触角最高达160.03°;制备的超疏水表面结构在室温环境下具有长期的稳定性。

By vacuum/pressuer bag mouding techniques,a glass fibers reinforced epoxy composite materials which has the functional layer of CaCO3 and epoxy resin were prepared.A method to form superhydrophobic surface on the glass reinforced epoxy composite materials by chemical etching and surface modifing technique was investigated.The morphologies and superhydrophobicity were analyzed by scanning electron microscopy(SEM) and water contact angle measurement.The results showed that the micro/nano-binary porous structure was formed on surface of the glass reinforced epoxy composite materials and the water contact angle value of the surface was up to 160.03°.In addition,stored in an ambient environment,the as-prepared superhydrophobic surface has essentially stability.

参考文献

[1] Qian BT;Shen ZQ .Fabrication of superhydrophobic surfaces by dislocation-selective chemical etching on aluminum, copper, and zinc substrates[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(20):9007-9009.
[2] Huan Liu;Lin Feng;Jin Zhai;Lei Jiang;Daoben Zhu .Reversible Wettability of a Chemical Vapor Deposition Prepared ZnO Film between Superhydrophobicity and Superhydrophilicity[J].Langmuir: The ACS Journal of Surfaces and Colloids,2004(14):5659-5661.
[3] Satish A. Mahadik;Mahendra S. Kavale;S.K. Mukherjee;A. Venkateswara Rao .Transparent Superhydrophobic silica coatings on glass by sol-gel method[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2010(2):333-339.
[4] Liu, M.;Jia, Z.;Liu, F.;Jia, D.;Guo, B. .Tailoring the wettability of polypropylene surfaces with halloysite nanotubes[J].Journal of Colloid and Interface Science,2010(1):186-193.
[5] Wang, X.;Ye, Q.;Liu, J.;Liu, X.;Zhou, F. .Low surface energy surfaces from self-assembly of perfluoropolymer with sticky functional groups[J].Journal of Colloid and Interface Science,2010(1):261-266.
[6] Jinxin Yang;Pihui Pi;Xiufang Wen;Dafeng Zheng;Mengyi Xu;Jiang Cheng;Zhuoru Yang .A Novel Method To Fabricate Superhydrophobic Surfaces Based On Well-defined Mulberry-like Particles And Self-assembly Of Polydimethylsiloxane[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(6):3507-3512.
[7] Yang, H.;Jiang, P. .Scalable fabrication of superhydrophobic hierarchical colloidal arrays[J].Journal of Colloid and Interface Science,2010(2):558-565.
[8] Wei L;Parhi P;Vogler E A et al.Thickness-controlled hydrophobicity of fibrous parylene-C films[J].Materials Letters,2010,64:1063-1065.
[9] Wang L;Guo SJ;Hu XG;Dong SJ .Facile electrochemical approach to fabricate hierarchical flowerlike gold micro structures: Electrodeposited superhydrophobic surface[J].Electrochemistry communications,2008(1):95-99.
[10] Lining Pan;Huiru Dong;Pengyu Bi .Facile preparation of superhydrophobic copper surface by HNO3 etching technique with the assistance of CTAB and ultrasonication[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2010(5):1707-1711.
[11] Wenzel R N .Sur~ace roughness and contact angle[J].Phy Colloid Chem,1949,53:1466-1467.
[12] Cassie A B D;Baxter S .Wettability 0f porous surfaces[J].Transactions of the Faraday Society,1944,40:546-551.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%