报道了La3Ga5SiO14(LGS)同构物掺杂性改进后,用提拉法生长出A3BGa3Si2O14(A=Ca2+,Sr2+;B=Nb5+,Ta5+)系列的4种晶体.此类稀土晶体均为单轴晶,属三方晶系,32点群.采用改造过的分光光度计研究了这类晶体的透过率、旋光角、旋光率色散,并与LGS进行了比较.透射率光谱显示,ABGS类晶体在大于294 nm的可见光谱区和红外区是透明的,透过率均大于LGS.偏振光透过率曲线显示这类晶体自然旋光率较大,结果表明,这4种晶体的旋光率均大于LGS,其中SNGS旋光为最大,在波长0.30 μm处,ρ=240.75(°)·mm-1;在0.633 μm处,ρ=34.73(°)·mm-1.根据实验结果计算了这类晶体的波尔兹曼系数,与文献结果吻合很好.
参考文献
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