利用界面聚合法对问位芳纶进行表面接枝改性,制备出新型具有液晶性能的芳纶.采用傅立叶转换红外光谱(FT-IR)对芳纶表面结构进行表征.由扫描电子显微镜(SEM)照片可以看出,改性后的芳纶表面变得粗糙,改性后纤维直径约为20μm.利用差示扫描量热法(DSC)对改性后纤维进行热性能分析,结果表明纤维具有液晶性能,在升、降温过程中的介晶相范围分别为192℃~237℃和147℃~209℃.接枝改性后的芳纶可以增加纤维与基体间的界面粘合性,提高复合材料的力学性能.
参考文献
[1] | Zhang AL.;Zhang BY.;Feng ZL. .Compatibilization by main-chain thermotropic liquid crystalline ionomer of blends of PBT/PP[J].Journal of Applied Polymer Science,2002(5):1110-1117. |
[2] | 张爱玲,张宝砚,吴艳英,丁艳梅.液晶聚合物对尼龙1010/聚丙烯共混合金的结晶行为和力学性能的影响[J].高分子材料科学与工程,2001(06):71-74. |
[3] | Wu SR.;Shyu SS.;Sheu GS. .KEVLAR FIBER-EPOXY ADHESION AND ITS EFFECT ON COMPOSITE MECHANICAL AND FRACTURE PROPERTIES BY PLASMA AND CHEMICAL TREATMENT[J].Journal of Applied Polymer Science,1996(9):1347-1360. |
[4] | Liu L;Huang YD;Zhang ZQ;Yang XB .Effect of ultrasound on wettability between aramid fibers and epoxy resin[J].Journal of Applied Polymer Science,2006(6):3172-3177. |
[5] | Wu J;Cheng XH .Interfacial studies on the surface modified aramid fiber reinforced epoxy composites[J].Journal of Applied Polymer Science,2006(5):4165-4170. |
[6] | Eisenbach C.D.;Goeldel A.;Noolandi J.;Shi A.C.;Hofmann J. .Miscibility of rigid-rod and random-coil macromolecules through acid-base interactions[J].Macromolecules,1999(5):1463-1470. |
[7] | JUNGE ZHI;BAOYAN ZHANG;YANYING WU;ZHILIU FENG .Study on a Series of Main-Chain Liquid-Crystalline Ionomers Containing Sulfonate Groups[J].Journal of Applied Polymer Science,2001(9):2210-2218. |
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