作者在熔盐中研究了Al的氧化/还原电位,作图法求得为-1.122V,阳极溶解为Al→Al~(3+)+3e用稳态法研究阴极过程,对一些离子的析出电位、AlCl_4~-扩散系数和Al~(3+)还原反应动力学参数进行了测量和讨论。
The standard oxidation/reduction potential of Al including its valence state in fused salt was examined, The anodic dissolution of Al can be shown by the equation Al→Al~3+3e. The standard oxidation/reduction potential of Al in fused salt is-1.122V as obtained by graphical method. Cathodic process has been investigated by means of steady state method. Separate potentials of some ions, the coefficient of diffusion ,of AlCl_4~- ion and kinetic constants of Al ion reduction have been meastured and discussed.
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