在水热条件下,合成了一个二维配位聚合物{ [Zn2(L) (m-bix)]2·0.5(H2O)}n[H4L=5,5’-亚甲基二间苯二甲酸,m-bix=1,3-双(咪唑基-1-甲基)-苯],并通过红外和X-射线单晶衍射进行了表征.X-射线衍射结果表明,该配位聚合物晶体属于三斜晶系,P-1空间群,a=1.10294(17) nm,b=1.10806(15) nm,c=1.2605(2) nm,α=73.259(2)°,β=74.304(3)°,γ=67.576(2)°,V=1.3410(4) nm3,Z=1.配位聚合物中,Zn(Ⅱ)原子采取四面体构型,三个氧原子分别来与三个L4-配体,一个氮原子来于配位的m-bix分子.每个L4-配体桥联六个Zn(Ⅱ)中心,形成一个波浪状的二维面[Zn2(L)]∞,然后m-bix分子在[Zn2(L)]∞的上下方连结双核Zn(Ⅱ)单元,形成二维层状化合物[Zn2 (L) (m-bix)]∞.室温下研究了配位聚合物的固体荧光光谱特性.
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