运用AMPS软件结合相关实验数据,利用微晶硅带隙与材料晶相比的关系,对pin型微晶硅薄膜太阳电池i层带隙渐变结构的总光生载流子产额、载流子复合速率等参数进行了模拟,并与普通pin型微晶硅薄膜太阳电池进行了对比分析.结果表明,一方面带隙渐变结构增加了进入微晶硅i层作为活性层的光吸收;另一方面渐变各层之间存在缺陷和复合中心,影响载流子收集.对于带隙递增型微晶硅(μc-Si:H)薄膜太阳电池,当i层总厚度为1.2μm时.其光电转化效率为14.843%.
参考文献
[1] | Meier J.;Dubail S.;Golay S.;Kroll U.;Fay S.;Vallat-Sauvain E. Feitknecht L.;Dubail J.;Shah A. .Microcrystalline silicon and the impact on micromorph tandem solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(1/4):457-467. |
[2] | Rech B et al.New materials and deposition techniques for highly eficient silicon thin film solar cells[J].Solar Energy Materials and Solar Cells,2002,74:4397. |
[3] | Nasuno Y.;Kondo M.;Matsuda A. .Microcrystalline silicon thin-film solar cells prepared at low temperature using PECVD[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(1/4):497-503. |
[4] | Pieters B E et al.Determination of the mobility gap of intrinsic in p-i-n solar cells[J].Journal of Applied Physics,2009,105(04):044502. |
[5] | Rafata N H et al.Numerical simulation of the limiting efficiency of the graded bandgap solar cell[J].Renewable Energy,2007,32:21. |
[6] | Dharmadasa IM;Chaure NB;Tolan GJ;Samantilleke AP .Development of p(+), p, i, n, and n(+)-type CuInGaSe2 layers for applications in graded bandgap multilayer thin-film solar cells[J].Journal of the Electrochemical Society,2007(6):H466-H471. |
[7] | Sassi G et al.Theoretic alanalysis of solar cells based on graded band-gap structures[J].Journal of Applied Physics,1983,54(09):5421. |
[8] | Konagai M;Takahashi K et al.Graded-band-gap pGa1-x-AlxAs-nGaAs heterojunction solar cells[J].Journal of Applied Physics,1975,46(08):3542. |
[9] | Gloeckler, M;Sites, JR .Band-gap grading in Cu(In,Ga)Se-2 solar cells[J].The journal of physics and chemistry of solids,2005(11):1891-1894. |
[10] | 彭华,周之斌,崔容强,叶庆好,庞乾骏,陈鸣波,赵亮.渐变带隙结构在Ⅲ-Ⅴ族太阳电池中的应用[J].半导体学报,2005(05):958-964. |
[11] | Pieters B E et al.Optimization of α-SiGe:H solar cells with graded intrinsic layers using integrated optical and electrical modeling[J].Thin Solid Films,2004,451-452:294. |
[12] | Zimmer J.;Wagner H.;Stiebig H. .a-SiGe : H based solar cells with graded absorption layer[J].Journal of Applied Physics,1998(1):611-617. |
[13] | Xu X et al.Band edge discontinuities between microcrystalline and amorphous hydrogenated silicon alloys and their effect on solar cell performance[J].Applied Physics Letters,1995,67(16):2323. |
[14] | S. Hamma;P. Roca i Cabarrocas .Determination of the mobility gap of microcrystalline silicon and of the band discontinuities at the amorphous/microcrystalline silicon interface using in situ Kelvin probe technique[J].Applied physics letters,1999(21):3218-3220. |
[15] | Nath M et al.The open-circuit voltage in microcrystalline silicon solar cells of different degrees of crystallinity[J].Thin Solid Films,2008,516:6974. |
[16] | Kanschat P et al.Defect and tail states in microcrystalline silicon investigated by pulsed ESR[J].Materials Research Society Symposium Proceedings,2000,609:A27.3.1. |
[17] | Strengers JJH;Rubinelli FA;Rath JK;Schropp REI .A combined experimental and computer simulation study of HWCVD nip micro crystalline silicon solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(1/2):291-294. |
[18] | Matsuura H et al.Electrical properties of n-amorphous/pcrystalline silicon heterojunctions[J].Journal of Applied Physics,1984,55:1012. |
[19] | Schmidt M;Korte L;Laades A;Stangl R;Schubert CH .Physical aspects of a-Si : H/c-Si hetero-junction solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2007(19):7475-7480. |
[20] | Chan, KY;Knipp, D;Gordijn, A;Stiebig, H .Influence of crystalline volume fraction on the performance of high mobility microcrystalline silicon thin-film transistors[J].Journal of Non-Crystalline Solids,2008(19/25):2505-2508. |
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