多孔金属-有机配位聚合物(Metal-Organic Coordination Polymers-MOCPs)是一种新型功能材料,可通过其构件分子(金属离子和有机配体分子)的组合对孔穴大小、形状和表面特性进行调控,从而赋于它独特的结构和特性,在催化性能、分子识别、气体吸附、光学、磁性材料等方面具有诱人的发展前景.本文系统介绍了MOCPs在催化性能上的研究进展及其合成途径,并对MOCPs酶模拟体系在传感器方面的应用进行了展望.
参考文献
[1] | 孙为银.配位化学[A].北京:化学工业出版社,2004 |
[2] | J Y Lu .[J].Coordination Chemistry Reviews,2003,246:327-347. |
[3] | Yaghi OM.;O'Keeffe M.;Ockwig NW.;Chae HK.;Eddaoudi M.;Kim J. .Reticular synthesis and the design of new materials [Review][J].Nature,2003(6941):705-714. |
[4] | Kitagawa S;Noro S.[J].Chemical Communications,2002(03):222-223. |
[5] | Schiller A;Scopelliti R;Severin K .Enhanced hydrolytic activity of Cu(II) and Zn(II) complexes in highly cross-linked polymers[J].Dalton transactions: An international journal of inorganic chemistry,2006(32):3858-3867. |
[6] | Partha M;Giridhar M;Srinivasan N.[J].Journal of Physical Chemistry B,2006:99. |
[7] | Kim Y;Kim SJ;Choi SH;Han JH;Nam SH;Lee JH;Kim HJ;Kim C;Kim DW;Jang HG .Crystal structures and catalytic activities of Zn(II) compounds containing 1,3-bis(4-pyridyl)propane[J].Inorganica Chimica Acta,2006(8):2534-2542. |
[8] | Wasuke M;Tomohiko S et al.[J].Journal of Solid State Chemistry,2005,178:2555-2573. |
[9] | John M;Jose J;Mathew B .Effect of the degree of NNMBA crosslinking on the physicochemical characteristics and catalytic activity of 4-20 mol% NNMBA-crosslinked polyacrylic acid-metal complexes[J].Journal of Macromolecular Science. Pure and Applied Chemistry,2004(1):85-105. |
[10] | Luc Alaerts;Etienne Seguin;Hilde Poelman .Probing the Lewis Acidity and Catalytic Activity of the Metal-Organic Framework [Cu_3(btc)_2] (BTC=Benzene-l,3,5-tricarboxylate)[J].Chemistry: A European journal,2006(28):7353-7363. |
[11] | Xiaodan Guo;Guangshan Zhu.[J].Chemical Communications,2006:3172-3174. |
[12] | Gomez-Lor, B;Gutierrez-Puebla, E;Iglesias, M;Monge, MA;Ruiz-Valero, C;Snejko, N .Novel 2D and 3D indium metal-organic frameworks: Topology and catalytic properties[J].Chemistry of Materials,2005(10):2568-2573. |
[13] | B Kesanli;W Lin .[J].Coordination Chemistry Reviews,2003,246:305-326. |
[14] | Haines A H.Methods for the Oxidation of Organic Compounds[M].Academics:London,1985 |
[15] | Danil N Dybtsev;Alexey L Nuzhdin et al.[J].Angewandte Chemie International Edition,2006,45:916-920. |
[16] | Evanhoe R .[J].Chemical and Engineering News,2006,84(26):8-39. |
[17] | M Fujita;K Umemoto.[J].Chemical Communications,2001:509-518. |
[18] | J Perles;M Iglesias.[J].Chemical Communications,2003:346-347. |
[19] | 反应条件:硫化物浓度为0.05molL-1,室温,反应16h[M]. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%