采用射频磁控溅射TiO2陶瓷靶的方法在硅和石英衬底上制备纳米TiO2薄膜,并经950℃退火1h.通过X射线衍射(XRD)、原子力显微镜(AFM)、紫外可见光谱(UV-Vis)和接触角仪对薄膜相结构、表面形貌、光学性能和亲水性能进行表征.结果表明,与950℃退火1h相比,未退火薄膜是无定形结构并呈现较高的光致亲水性能.退火薄膜是锐钛矿和金红石混合相,其中锐钛矿相质量分数是11.34%.未退火和950℃退火1h的薄膜样品的能隙分别是3.03 eV和3.11 eV.未退火薄膜具有较高的光致亲水性能主要归因于其较低的光学能隙.退火薄膜的热致亲水性能与其相结构、表面清洁度和粗糙度有关.
参考文献
[1] | Wang R;HashimotoK;FujishimaA et al.Light-Induced Amphiphilic Surfaces[J].Nature,1997,388(31):431-432. |
[2] | Chia-Hsin Li;Yung-Hsu Hsieh;Wan-Ting Chiu .Study on preparation and photocatalytic performance of Ag/TiO2 and Pt/TiO2 photocatalysts[J].Separation and Purification Technology,2007(1):148-151. |
[3] | Yang, C;Fan, HQ;Xi, YX;Chen, J;Li, Z .Effects of depositing temperatures on structure and optical properties of TiO2 film deposited by ion beam assisted electron beam evaporation[J].Applied Surface Science,2008(9):2685-2689. |
[4] | 田琳琳,姚兰芳,许瑞清,康俊龙,李林,王硕.铋铁共掺纳米TiO2复合薄膜的制备及光催化性能[J].人工晶体学报,2011(03):710-715. |
[5] | 包镇红,江伟辉,苗立锋,朱庆霞.非水解和水解溶胶-凝胶法制备TiO2薄膜的对比研究[J].人工晶体学报,2011(04):932-937. |
[6] | 周明飞,孟凡明,孙兆奇,宋学萍.退火温度对TiO2薄膜结构、组分和光学性能的影响[J].人工晶体学报,2008(02):411-416. |
[7] | Mardare D.;Delibas M.;Rusu GI.;Tasca M. .On the structural properties and optical transmittance of TiO2 r.f. sputtered thin films[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2000(1/4):200-206. |
[8] | Tang H;Prasad K;Sanjinès R et al.Electrical and Optical Properties of TiO2 Anatase Thin Films[J].Journal of Applied Physics,1994,75(04):2042-2047. |
[9] | D. Mardare;G.I. Rusu;F. Iacomi .Chromium-doped titanium oxide thin films[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2005(1/3):187-191. |
[10] | Diana Mardare;Felicia Iacomi;D. Luca .Substrate and Fe-doping effects on the hydrophilic properties of TiO2 thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2007(16):6474-6478. |
[11] | Tauc J .Absorption Edge and Internal Electric Fields in Amorphous Semiconductors[J].Materials Research Bulletin,1970,5(08):721-729. |
[12] | Chou HY;Lee EK;You JW;Yu SS .Photo-induced hydrophilicity of TiO2-N-x(x) thin films on PET plates[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2007(2/4):189-192. |
[13] | Ye Q;Liu PY;Tang ZF;Zhai L .Hydrophilic properties of nano-TiO2 thin films deposited by RF magnetron sputtering[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2007(5):627-631. |
[14] | Tien-Syh Yang;Ching-Bin Shin;Ming-Show Wong .Structure and hydrophilicity of titanium oxide films prepared by electron beam evaporation[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,2004(1/3):75-82. |
[15] | Karuppuchamy S;Jeong JM;Amalnerkar DP;Minoura H .Photoinduced hydrophilicity of titanium dioxide thin films prepared by cathodic electrodeposition[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2006(5):494-498. |
[16] | Y.K. Du;Y.Q. Gan;P. Yang;F. Zhao;N.P. Hua;L. Jiang .Improvement in the heat-induced hydrophilicity of TiO_2 thin films by doping Mo(VI) ions[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2005(1/2):133-136. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%