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通过溶剂热的方法合成了石墨烯-镍铁氧体纳米复合材料(NFR).采用X射线衍射仪(XRD)、拉曼光谱仪(Raman)、傅立叶红外光谱仪(FT-IR)以及透射电镜(TEM)等仪器对样品的形貌和结构进行了表征,并将其作为锂离子电池负极材料组装成模拟电池,考察其电化学性能.测试结果表明:NFR纳米复合材料在100mA·g-1电流密度首圈放电比容量高达1223mAh·g-1,首次可逆比容量为830mAh·g-1,100圈充放电后,容量几乎无衰减,保持较好的循环稳定性.这种优异的性能归功于复合材料中镍铁氧体和石墨烯之间的协同作用.

参考文献

[1] Liang, Chaolun;Huang, Senchuan;Zhao, Wenxia;Liu, Wenyue;Chen, Jian;Liu, Hong;Tong, Yexiang.Polyhedral Fe3O4 nanoparticles for lithium ion storage[J].New Journal of Chemistry,20154(4):2651-2656.
[2] Peiyi Zhu;Shuangyu Liu;Jian Xie;Shichao Zhang;Gaoshao Cao;Xinbing Zhao.Facile Synthesis of NiFe2O4/Reduced Graphene Oxide Hybrid with Enhanced Electrochemical Lithium Storage Performance[J].材料科学技术(英文版),2014(11):1078-1083.
[3] 李涛 .Fe-Mn-Ti-C锂离子电池负极材料的制备及其电化学性能研究[D].山东大学,2015.
[4] 张加艳;沈建兴;魏长宝.锂离子电池负极材料研究进展[J].山东陶瓷,2015(1):7-10,28.
[5] Yongsheng Fu;Yunhai Wan;Hui Xia;Xin Wang.Nickel ferrite-graphene heteroarchitectures: Toward high-performance anode materials for lithium-ion batteries[J].Journal of Power Sources,2012Sep.1(Sep.1):338-342.
[6] Min Fu;Qingze Jiao;Yun Zhao.Preparation of NiFe2O4 nanorod-graphene composites via an ionic liquid assisted one-step hydrothermal approach and their microwave absorbing properties[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201318(18):5577-5586.
[7] 杨光;陈野川;薛卫东;赵睿.锂离子负极材料NiFe2O4/Graphene复合材料的制备和电化学性能[J].化工科技,2014(5):16-19.
[8] Nana Wang;Huayun Xu;Liang Chen;Xin Gu;Jian Yang;Yitai Qian.A general approach for MFe_2O_4 (M=Zn, Co, Ni) nanorods and their high performance as anode materials for lithium ion batteries[J].Journal of Power Sources,2014Feb.1(Feb.1):163-169.
[9] Haowen Liu;Hua Zhu;Hanmin Yang.A low temperature synthesis of nanocrystalline spinel NiFe_2O_4 and its electrochemical performance as anode of lithium-ion batteries[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,20134(4):1587-1592.
[10] 汤慕尧;贺春华;张海燕;林锦;成正东.有无液晶性的氧化石墨烯之间的差异[J].材料科学与工程学报,2015(2):203-206,267.
[11] 邹鹏;石文荣;杨书华;黄德欢.石墨烯的化学气相沉积法制备及其表征[J].材料科学与工程学报,2014(2):264-267.
[12] Kuldeep Singh;Anil Ohlan;Viet Hung Pham.Nanostructured graphene/Fe3O4 incorporated polyaniline as a high performance shield against electromagnetic pollution[J].Nanoscale,20136(6):2411-2420.
[13] Xianglan Chen;Bin Cheng;Huayun Xu.Porous ZnFe2O4 Nanospheres Grown on Graphene Nanosheets as a Superior Anode Material for Lithium Ion Batteries[J].Chemistry Letters,20126(6):639-641.
[14] C. Nethravathi;T. Nisha;N. Ravishankar.Graphene-nanocrystalline metal sulphide composites produced by a one-pot reaction starting from graphite oxide[J].Carbon,20098(8):2054-2059.
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