以双丙酮丙烯酰胺(DAAM)作为官能单体,制备了含有酮羰基的聚丙烯酸酯乳液.将此乳液与己二酸二酰肼(ADH)混合,制备了空调铝箔用涂料.讨论了DAAM的量对乳液凝胶率、涂膜吸水率、耐腐蚀性、耐划性能、热分解性能的影响,并且通过FT-IR对聚合物结构进行表征.结果表明,随着DAAM的量的增加,聚丙烯酸酯乳液的凝胶率增大,乳液稳定性变差,涂膜的耐水性、耐划性、耐腐蚀性增强,而热稳定性减弱.
参考文献
| [1] | 吕晓莉.酮肼交联反应在乳液聚合物中的应用研究[M].桂林:广西大学出版社,2008 |
| [2] | 卢杰宏;王 峰;胡剑青 等.酮胼交联对涂料印花用聚丙烯酸酯乳液的影响[J].功能高分子学报,2012,42(01):20-23. |
| [3] | Alexander Diethert;Yana Peykova;Norbert Willenbacher .Near-Surface Composition Profiles and the Adhesive Properties of Statistical Copolymer Films Being Model Systems of Pressure Sensitive Adhesive Films[J].ACS applied materials & interfaces,2010(7):2060-2068. |
| [4] | Tiarks F.;Frechen T.;Kirsch S.;Leuninger J.;Melan M.;Pfau A.;Richter F.;Schuler B.;Zhao CL. .Formulation effects on the distribution of pigment particles in paints[J].Progress in Organic Coatings: An International Review Journal,2003(2/4):140-152. |
| [5] | Bethencourt M.;Botana FJ.;Cano MJ.;Osuna RM.;Marcos M. .Degradation mechanism of an acrylic water-based paint applied to steels [Review][J].Progress in Organic Coatings: An International Review Journal,2003(2):164-168. |
| [6] | Holtz R D;Lima B A;Souza Filho A G et al.Nanostructured silver vanadate as a promising antibacterial additive to water-based paints[J].NANOMEDICINE:NANOTECHNOLOGY BIOLOGY AND MEDICINE,2012,8(06):935-940. |
| [7] | Karaka?, F.;?elik, M.S. .Effect of quantity and size distribution of calcite filler on the quality of water borne paints[J].Progress in Organic Coatings: An International Review Journal,2012(3):555-563. |
| [8] | 江镇海.双丙酮丙烯酰胺在涂料中的应用[J].中国涂料,2005(02):10-12. |
| [9] | 项尚林,薛志杰.双丙酮丙烯酰胺对聚丙烯酸酯压敏胶性能的影响[J].粘接,2008(08):18-20. |
| [10] | 叶彦春,初立秋,陈煜,谭惠民.双丙酮丙烯酰胺在固体推进剂粘合体系中的应用[J].精细化工,2008(07):704-707. |
| [11] | 杨建军,张建安,吴庆云,吴明元,瞿贤超,崔国庭,王小君,唐礼道.酮肼交联型丙烯酸酯-聚氨酯涂料印花黏合剂[J].纺织学报,2008(02):68-72. |
| [12] | 赵静,沈一丁,赖小娟.酮肼交联及硅烷偶联水性聚氨酯的成膜机理及其性能研究[J].高分子学报,2010(09):1122-1128. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%