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冷轧厂电镀锡生产过程中产生的废水含有大量的有机物,COD浓度高,pH值在1.1~2.0之间,很难直接进行生化处理。为提高生化处理效果,以H2O2铁炭柱pH调节混凝为处理工艺进行前处理,结果表明,空速为3 h-1、H2O2/COD为1.5(质量比)、pH为8左右、PAM加入量为15 mg/m3时处理效果最好。利用该方法处理冷轧厂镀锡废水,可有效降低COD的浓度, Sn2+被氧化成高价态后沉淀除去,为废水进入后续的生化处理提供了保障。

There is a plenty of organic matters in wastewater from tin electroplating process of cold rolling mill.The concentration of COD is high and pH is between 1.12.0.So it is difficult to treat directly by biochemical process. H2O2ferric/activated carbonpH calibrationcoagulation process was used to pretreat such wastewater. The results showed that the effect is the best when void speed is 3 h-1, H2O2/COD is 1.5, pH is about 8 and the dosage of PAM is 5 mg/m3.The chemical oxygen demands (COD) can be reduced and the Sn2+ removed by precipitation as Sn4+ after oxidation.The pretreatment provides necessary conditions for the further biological process.

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