以碳纳米管和纸纤维混合制成均匀液体经抽滤制备成复合导电纸.采用不同工艺将石墨化碳纳米管和纸纤维复合,通过四探针电阻仪表征表面电阻和XRD、TEM、SEM等表征内部结构.将制备的导电纸作为集流体,采用CT-3008W-5 V5 mA-S4检测仪测试锌锰纸电池电化学性能.结果表明,当碳纳米管与纸浆质量比为2∶1时,表面电阻为20Ω/□,碳纳米管与纸纤维复合效果最佳.使用碳纳米管导电纸作集流体时,和石墨集流体相比,放电时间增加36.7% ~ 122.4%,电池质量能量密度提高64.1% ~ 141%.碳纳米管导电纸作集流体能大幅提高电池的能量密度.
参考文献
[1] | Mauricio Terrones .SCIENCE AND TECHNOLOGY OF THE TWENTY-FIRST CENTURY: Synthesis, Properties, and Applications of Carbon Nanotubes[J].Annual review of materials research,2003(0):419-501. |
[2] | 王孝恩,孙玉泉.单壁碳纳米管与新型储氢材料[J].天津化工,2009(01):34-37. |
[3] | 赵晋津,任书霞,杜彦良,朱文华,汪文娜,孔丽娟,卢雪.碳纳米管对硅酸盐水泥力学性能的影响研究[J].硅酸盐通报,2013(07):1361-1366,1370. |
[4] | Liangbing Hu;Yi Cui .Energy and environmental nanotechnology in conductive paper and textiles[J].Energy & environmental science: EES,2012(4):6423-6435. |
[5] | Liangbing Hu;Jang Wook Choi;Yuan Yang;Sangmoo Jeong;Fabio La Mantia;Li-Feng Cui;Yi Cui .Highly conductive paper for energy-storage devices[J].Proceedings of the National Academy of Sciences of the United States of America,2009(51):21490-21494. |
[6] | Hu, L.;Wu, H.;La Mantia, F.;Yang, Y.;Cui, Y. .Thin, flexible secondary Li-ion paper batteries[J].ACS nano,2010(10):5843-5848. |
[7] | Thu H Nguyen;Arwa Fraiwan;Seokheun Choi.Paper-based batteries: A review[J].Biosensors & Bioelectronics: The International Journal for the Professional Involved with Research, Technology and Applications of Biosensers and Related Devices,2014:640-649. |
[8] | Leif Nyholm;Gustav Nystrom;Albert Mihranyan;Maria Stromme .Toward Flexible Polymer and Paper-Based Energy Storage Devices[J].Advanced Materials,2011(33):3751-3769. |
[9] | Nystrom, G;Razaq, A;Stromme, M;Nyholm, L;Mihranyan, A .Ultrafast All-Polymer Paper-Based Batteries[J].Nano letters,2009(10):3635-3639. |
[10] | Lee KB .Two-step activation of paper batteries for high power generation: design and fabrication of biofluid- and water-activated paper batteries[J].Journal of Micromechanics and Microengineering,2006(11):2312-2317. |
[11] | Caiyun Wang;Dan Li;Chee O. Too .Electrochemical Properties of Graphene Paper Electrodes Used in Lithium Batteries[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(13):2604-2606. |
[12] | Lara Jabbour;Matteo Destro;Claudio Gerbaldi;Didier Chaussy;Nerino Penazzi;Davide Beneventi .Use of paper-making techniques for the production of Li-ion paper-batteries[J].Nordic pulp and paper research journal,2012(2):472-475. |
[13] | Wang D;Song PC;Liu CH;Wu W;Fan SS .Highly oriented carbon nanotube papers made of aligned carbon nanotubes[J].Nanotechnology,2008(7):75609-1-75609-6-0. |
[14] | Bunshi Fugetsu;Eiichi Sano;Masaki Sunada .Electrical conductivity and electromagnetic interference shielding efficiency of carbon nanotube/cellulose composite paper[J].Carbon: An International Journal Sponsored by the American Carbon Society,2008(9):1256-1258. |
[15] | Highly strong and conductive carbon nanotube/cellulose composite paper[J].Composites science and technology,2010(10):P.1564. |
[16] | Cao AY.;Liang J.;Wu DH.;Wei BQ.;Xu CL. .X-ray diffraction characterization on the alignment degree of carbon nanotubes[J].Chemical Physics Letters,2001(1/2):13-17. |
[17] | Rinzler AG.;Dai H.;Nikolaev P.;Huffman CB.;Rodriguez-Macias FJ.;Boul PJ.;Lu AH.;Heymann D.;Colbert DT.;Lee RS.;Fischer JE.;Rao AM.;Eklund PC.;Smalley RE.;Liu J. .Large-scale purification of single-wall carbon nanotubes: process, product, and characterization[J].Applied physics, A. Materials science & processing,1998(1):29-37. |
[18] | G.Ovejero;J.L.Sotelo;M.D.Romero;A.Rodriguez;M.A.Ocana;G.Rodriguez;J.Garcia .Multiwalled Carbon Nanotubes for Liquid-Phase Oxidation.Functionalization,Characterization,and Catalytic Activity[J].Industrial & Engineering Chemistry Research,2006(7):2206-2212. |
[19] | Xuesong Li;Hongwei Zhu;Lijie Ci;Cailu Xu;Zongqiang Mao;Bingqing Wei;Ji Liang;Dehai Wu .Hydrogen uptake by graphitized multi-walled carbon nanotubes under moderate pressure and at room temperature[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(13):2077-2079. |
[20] | Xuesong Li;Hongwei Zhu;Lijie Ci;Cailu Xu;Zongqiang Mao;Bingqing Wei;Ji Liang;Dehai Wu .Hydrogen uptake by graphitized multi-walled carbon nanotubes under moderate pressure and at room temperature[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(13):2077-2079. |
[21] | Ayumu Yasuda;Noboru Kawase;Florian Banhart;Wataru Mizutani;Tetsuo Shimizu;Hiroshi Tokumoto .Graphitization Mechanism during the Carbon-Nanotube Formation Based on the In-Situ HRTEM Observation[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2002(8):1849-1852. |
[22] | R.Andrews;D.Jacques;D.Qian;E.C.Dickey .Purification and structural annealing of multiwalled carbon nanotubes at graphitization temperatures[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(11):1681-1687. |
[23] | Yao Wang;Jun Wu;Fei Wei .A treatment method to give separated multi-walled carbon nanotubes with high purity,high crystallization and a large aspect ratio[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(15):2939-2948. |
[24] | Hongjie Dai .Carbon nanotubes:synthesis,integration,and properties[J].Accounts of Chemical Research,2002(12):1035-1044. |
[25] | Random networks of carbon nanotubes as an electronic material[J].Applied physics letters,2003(13):2145-2147. |
[26] | L.Hu;D.S.Hecht;G.Gruner .Percolation in Transparent and Conducting Carbon Nanotube Networks[J].Nano letters,2004(12):2513-2517. |
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