用高温固相反应法制备了非化学计量性固体电解质Ba0.98Ce0.9Y0.1O3-α,分别用氢浓差电池及氧浓差电池方法研究了在600～1000℃范围Ba0.98Ce0.9Y0.1.1O3-α的离子导电特性.结果表明,Ba0.98Ce0.9.9Y01O3-α固体电解质在氢气气氛中几乎为纯质子导体,而在氧气气氛中为氧离子和电子空穴混合导体.
参考文献
| [1] | IWAHARA H;Shimura T;Matsumoto H .[J].ELECTROCHEMISTRY,2000,68(03):154. |
| [2] | IWAHARA H .[J].Solid State Ionics,1996,86-88:9. |
| [3] | IWAHARA H;Yajima T;Uchida H.Proceedings of the Second International Symposium on Solid Oxide Fuel Cells[C].Athens Greece,1991 |
| [4] | IWAHARA H;Yajima T;Hibino T et al.[J].Journal of the Electrochemical Society,1993,140:1687. |
| [5] | Meng GY.;Gu YF.;Peng DK.;Wang P. .Preparation and characterization of barium cerate-based thick membranes using a screen printing process[J].Solid state ionics,2000(Special Issue SI):209-213. |
| [6] | 蒋凯,何志奇,王鸿燕,梁宏伟,孟建,任玉芳,苏锵.BaCe0.8Ln0.2O2.9（Ln=Gd, Sm, Eu）固体电解质的低温制备及其燃料电池性质[J].中国科学B辑,1999(04):355-360. |
| [7] | 马桂林,贾定先,仇立干.BaCe0.9Y0.1O3-α固体电解质燃料电池性能[J].化学学报,2000(11):1340-1344. |
| [8] | Taniguchi N;Yasumoto E;Nakagiri Y et al.[J].Journal of the Electrochemical Society,1998,145(05):1744. |
| [9] | Kagakukai N .[J].Kikan Kagaku Sosetsu,1997,32:21. |
| [10] | Jacobson A J;Tofield B C;Fender B E .[J].Acta Crystallographica,1972,B28:956. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%