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通过机械球磨的方法成功制得Mg55Ni35Si10非晶粉末,并采用X射线衍射(XRD)对其非晶形成过程进行研究,发现Mg55Ni35Si10粉末样品在球料比为20:1、转速为600r/min的条件下,经过54h球磨后开始形成完全的非晶结构.还采用差示扫描量热仪(DSC)对Mg55Ni35Si10非晶粉末的热稳定性进行了研究,通过Kissinger方程得到样品开始晶化的表观激活能为(280.6±44.5)kJ/mol,与文献中报道的Mg65Cu25Gd10的激活能((285.2±27.6)kJ/mol)相近,说明样品具有较好的热稳定性.此外,还对Mg55Ni35Si10非晶在NaCl溶液中的腐蚀行为进行了研究,发现该样品的腐蚀电位远远正于AZ31和AZ61镁合金,表明Mg55Ni35Si10非晶具有较好的耐腐蚀性能.

参考文献

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