将天然产物如氨基酸、甾醇、核苷和糖类引入到取代聚乙炔侧链上,利用共轭多烯主链和功能性侧链的协同作用,聚合物表现出光学活性、液晶、刺激响应性、手性识别、生物相容性等新颖性能,在化学传感、信息储存、光学显示、手性探针、药物传递、组织工程等领域具有潜在的应用价值.文中综述了含天然产物分子侧基的取代聚乙炔衍生物的合成与性能,并指出了他们的发展趋势.
参考文献
[1] | Hideki Shirakawa .The discovery of polyacetylene film: the dawning of an era of conducting polymers (Nobel lecture)[J].Angewandte Chemie International Edition,2001(14):2575-2580. |
[2] | Alan G. MacDiarmid ."Synthetic metals": a novel role for organic polymers (Nobel lecture)[J].Angewandte Chemie International Edition,2001(14):2581-2590. |
[3] | Masuda T .Substituted polyacetylenes[J].Journal of Polymer Science, Part A. Polymer Chemistry,2007(2):165-180. |
[4] | Lam JWY;Tang BZ .Functional polyacetylenes[J].Accounts of Chemical Research,2005(9):745-754. |
[5] | Liu, JZ;Lam, JWY;Tang, BZ .Acetylenic Polymers: Syntheses, Structures, and Functions[J].Chemical Reviews,2009(11):5799-5867. |
[6] | Kento Okoshi;Koichi Sakajiri;Jiro Kumaki;Eiji Yashima .Well-Defined Lyotropic Liquid Crystalline Properties of Rigid-Rod Helical Polyacetylenes[J].Macromolecules,2005(10):4061-4064. |
[7] | Cheuk KKL.;Lam JWY.;Lai LM.;Dong YP.;Tang BZ. .Syntheses, hydrogen-bonding interactions, tunable chain helicities, and cooperative supramolecular associations and dissociations of poly(phenylacetylene)s bearing L-valine pendants: Toward the development of proteomimetic polyenes[J].Macromolecules,2003(26):9752-9762. |
[8] | Li BS.;Cheuk KKL.;Ling LS.;Chen JW.;Xiao XD.;Bai CL.;Tang BZ. .Synthesis and hierarchical structures of amphiphilic polyphenyl acetylenes carrying L-valine pendants [Review][J].Macromolecules,2003(1):77-85. |
[9] | Cheuk KKL.;Lam JWY.;Chen JW.;Lai LM.;Tang BZ. .Amino acid-containing polyacetylenes: Synthesis, hydrogen bonding, chirality transcription, and chain helicity of amphiphilic poly(phenylacetylene)s carrying L-leucine pendants [Review][J].Macromolecules,2003(16):5947-5959. |
[10] | Lo Ming Lai;Jacky Wing Yip Lam;Junwu Chen;Han Peng;Kevin Ka Leung Cheuk;Ben Zhong Tang .Synthesis and properties of cholesterol-containing poly(phenylacetylenes)[J].Polymer Preprints,2002(2):1128-1129. |
[11] | Lo Ming Lai;Jacky Wing Yip lam;Kevin Ka Leung Cheuk;Ben Zhong Tang .Synthesis, chirality, and liquid crystallinity of poly(phenylacetylenes) containing stigmasterol pendants[J].Polymer Preprints,2003(1):954-955. |
[12] | Bing Shi Li;Junwu Chen;Chuan Feng Zhu;Kevin K.L.Leung;Lijun Wan;Chunli Bai;Ben Zhong Tang .Formation of Porous Films and Vesicular Fibers via Self-Organization of an Amphiphilic Chiral Oligomer[J].Langmuir: The ACS Journal of Surfaces and Colloids,2004(6):2515-2518. |
[13] | Cheuk KKL;Lam JWY;Li BS;Xie Y;Tang BZ .Decorating conjugated polymer chains with naturally occurring molecules: Synthesis, solvatochromism, chain helicity, and biological activity of sugar-containing poly(phenylacetylene)s[J].Macromolecules,2007(8):2633-2642. |
[14] | Gao GZ.;Sanda F.;Masuda T. .Synthesis and properties of amino acid-based polyacetylenes[J].Macromolecules,2003(11):3932-3937. |
[15] | Rahim EA;Sanda F;Masuda T .Synthesis and properties of optically active amino acid based polyacetylenes bearing eugenol and fluorene moieties[J].Journal of Polymer Science, Part A. Polymer Chemistry,2006(2):810-819. |
[16] | Fumio Sanda;Hitoshi Araki;Toshio Masuda .Serine-Based Helical Polyacetylenes.Effect of Hydroxyl Group on the Secondary Structure[J].Macromolecules,2005(25):10605-10608. |
[17] | Fumio Sanda;Hitoshi Araki;Toshio Masuda .Synthesis and Properties of Serine- and Threonine-Based Helical Polyacetylenes[J].Macromolecules,2004(23):8510-8516. |
[18] | Zhao HC;Sanda F;Masuda T .Controlled helical orientation of carbazole in amino acid derived poly(N-propargylamide)s[J].Journal of Polymer Science, Part A. Polymer Chemistry,2007(2):253-261. |
[19] | Sanda F;Terada K;Masuda T .Synthesis, chiroptical properties, and pH responsibility of aspartic acid- and glutamic acid-based helical polyacetylenes[J].Macromolecules,2005(20):8149-8154. |
[20] | Haichao Zhao;Fumio Sanda;Toshio Masuda .Stimuli-responsive conjugated polymers.Synthesis and chiroptical properties of polyacetylene carrying L-glutamic acid and azobenzene in the side chain[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(8):2596-2602. |
[21] | Qu JQ;Shiotsuki M;Sanda F;Masuda T .Synthesis and properties of helical polyacetylenes carrying cholesteryl moieties[J].Macromolecular chemistry and physics,2007(8):823-832. |
[22] | Qu JQ;Sanda F;Masuda T .Synthesis and chiroptical properties of amino acid-derived poly(methylpropargyl ester)s[J].European Polymer Journal,2009(2):448-454. |
[23] | Qu JQ;Suzuki Y;Shiotsuki M;Sanda F;Masuda T .3-butyl-2-yl- and propargyl cholesteryl carbonates. chiroptical and liquid crystalline properties of their polymers[J].Macromolecular chemistry and physics,2007(18):1992-1999. |
[24] | Gao GZ.;Sanda F.;Masuda T. .Copolymerization of chiral amino acid-based acetylenes and helical conformation of the copolymers[J].Macromolecules,2003(11):3938-3943. |
[25] | Zhao HC;Sanda F;Masuda T .Tuning of fluorescence by controlling the secondary structure of amino acid-based poly(N-propargylamides) having pendant pyrene groups[J].Macromolecules,2004(24):8893-8896. |
[26] | Kong Xiangxing;Lam Wing Yip;Tang Ben Zhong;Wing Jacky .Synthesis, mesomorphism, isomerization, and aromatization of stereoregular poly{[4-({[6-({[4 prime -(heptyl) oxy-4-biphenylyl]carbonyl}oxy)-hexyl]oxy}carbonyl) phenyl]acetylene}[J].Macromolecules,1999(6):1722-1730. |
[27] | Fumio Sanda;Takuya Kawano;Toshio Masuda .Cyclopolymerization of Amino Acid-Based Diynes and Properties of the Obtained Polymers.Chiral Recognition and Metal Ion Extraction[J].Polymer bulletin,2005(5):341-347. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%