采用固相反应法在873 K合成了Pr2InNdO7光催化剂,通过X射线衍射(XID)、比表面积(BET)、光致发光(PL)和紫外-可见漫反射(UV-Vis DRS)测试手段对其进行了表征.以亚甲基蓝(MB)为光催化反应的模型化合物,在紫外和可见光的照射下对Pr2InNdO7光催化剂的活性进行了评价.结果表明:Pr、In、Nd的质量比对Pr2 InNdO7样品的光催化活性有重要的影响,当Pr、In、Nd的质量比为1:4:1时,Pr2 InNdO7样品的紫外和可见光催化活性分别达到最大值,并且它的光催化活性明显高于纯In2O3.这显著提高的光催化活性主要归功于适量的Pr2 O3、Nd2O5与In2 O3复合增加了它的比表面积,改善了光生电子-空穴对的分离效率以及提高了其在200~800 nm区域的光吸收强度.
参考文献
[1] | Chen S F;Yang Y G;Liu W .Preparation,characterization and activity evaluation of TiN/F-TiO2 photocatalyst[J].Journal of Hazardous Materials,2011,186(2-3):1560. |
[2] | Chen X B;Liu L;Yu P Y et al.Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals[J].Science,2011,331(6018):746. |
[3] | 李慧泉,洪文珊,崔玉民,华林,凡素华.晶相可调TiO2多孔薄膜的低温制备及其性能[J].材料导报,2012(20):73-77. |
[4] | 李慧泉,崔玉民,吴兴才,华林,洪文珊.具有不同Bi/Ti摩尔比的BiO(l)/TiO2(A)光催化剂的结构与性能[J].物理化学学报,2012(08):1985-1991. |
[5] | Shchukin D G;Schattka J H;Antonietti M et al.Photocatalytic properties of porous metal oxide networks formed by nanoparticle infiltration in a polymer gel template[J].Journal of Physical Chemistry B,2003,107(04):952. |
[6] | Jun Lv;Tetsuya Kako;Zhaosheng Li .Synthesis and Photocatalytic Activities of NaNbO3 Rods Modified by In2O3 Nanoparticles[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(13):6157-6162. |
[7] | Sakai A;Sakashita S;Sakashita M;Yasuda Y;Zaima S;Miyazaki S .Praseodymium silicate formed by postdeposition high-temperature annealing[J].Applied physics letters,2004(22):5322-5324. |
[8] | G. Lupina;T. Schroeder;J. Dabrowski;Ch. Wenger;A. U. Mane;H.-J. Mussig;P. Hoffmann;D. Schmeisser .Praseodymium silicate films on Si(100) for gate dielectric applications: Physical and electrical characterization[J].Journal of Applied Physics,2006(11):114109-1-114109-8-0. |
[9] | Dong F;Zhao WR;Wu ZB .Characterization and photocatalytic activities of C, N and S co-doped TiO2 with 1D nanostructure prepared by the nano-confinement effect[J].Nanotechnology,2008(36):365607-1-365607-10-0. |
[10] | 王学华,曹宏,吕飞,马懿超.La3+掺杂CdS/TiO2复合膜的制备及性能表征[J].化学与生物工程,2005(06):40-42. |
[11] | Kangwansupamonkon, W.;Jitbunpot, W.;Kiatkamjornwong, S. .Photocatalytic efficiency of TiO_2/poly[acrylamide-co-(acrylic acid)] composite for textile dye degradation[J].Polymer Degradation and Stability,2010(9):1894-1902. |
[12] | Wu Y M;Zhang J L;Xiao L et al.Preparation and characterization of TiC2 photocatalysts by Fe3+ doping together with Au deposition for the degradation of organic pollutants[J].Applied Catalysis B:Environmental,2009,88(3-4):525. |
[13] | Tang J W;Zou Z G;Ye J H .Photophysical and photocatalytic properties of AgInW2 O8[J].Journal of Physical Chemistry B,2003,107(51):14265. |
[14] | Yu J G;Yu H G;Cheng B et al.The effect of calcination temperature on the surface microstructure and photocatalytic activity of TiO2 thin films prepared by liquid phase deposition[J].Journal of Physical Chemistry B,2003,107(50):13871. |
[15] | Jing LQ;Qu YC;Wang BQ;Li SD;Jiang BJ;Yang LB;Fu W;Fu HG;Sun JZ .Review of photoluminescence performance of nano-sized semiconductor materials and its relationships with photocatalytic activity[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2006(12):1773-1787. |
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